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Lah, Myoung Soo
Nanoporous Materials Lab
Research Interests
  • Metal-Organic Frameworks (MOFs)

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Synthesis of Ru(II) complexes of N-heterocyclic carbenes and their promising photoluminescence properties in water

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Title
Synthesis of Ru(II) complexes of N-heterocyclic carbenes and their promising photoluminescence properties in water
Author
Son, SUPark, KHLee, YSKim, BYChoi, CHLah, Myoung SooJang, YHJang, DJChung, YK
Keywords
ROOM-TEMPERATURE LUMINESCENCE; EXCITED-STATE PROPERTIES; PHOTOPHYSICAL PROPERTIES; POLYPYRIDINE COMPLEXES; IMIDAZOLIUM SALTS; ARTIFICIAL PHOTOSYNTHESIS; RUTHENIUM(II) COMPLEXES; TRIDENTATE LIGANDS; ELECTRON-TRANSFER; METAL-COMPLEXES
Issue Date
200411
Publisher
AMER CHEMICAL SOC
Citation
INORGANIC CHEMISTRY, v.43, no.22, pp.6896 - 6898
Abstract
Novel complexes 1 and 2 based on N-heterocyclic carbenes, which are analogous to Ru(bpy)(3)(2+) and Ru(terpy)(2)(2+), respectively, were synthesized. The complex, which is analogous to Ru(terpy)(2)(2+), exhibited promising photoluminescence properties with a long lifetime of 820 ns in acetonitrile and 3100 ns in water at room temperature, respectively. In addition, ab initio calculations were carried out.
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DOI
http://dx.doi.org/10.1021/ic049514f
ISSN
0020-1669
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