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Lah, Myoung Soo
Frontier Energy Storage Material Lab.
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Three-dimensional helical coordination networks of a hexanuclear manganese metal lamacrocycle as a helical tecton

Author(s)
Moon, DSong, JKim, BJSuh, BJLah, Myoung Soo
Issued Date
2004-12
DOI
10.1021/ic049393j
URI
https://scholarworks.unist.ac.kr/handle/201301/6072
Fulltext
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=11144262080
Citation
INORGANIC CHEMISTRY, v.43, no.26, pp.8230 - 8232
Abstract
We report on helical coordination networks that were prepared using a hexanuclear manganese metallamacrocycle as a helical tecton. We were able to prepare the three-dimensional helical coordination networks using a hexanuclear manganese metallamacrocycle, [Mn6(lshz)6], as a helical tecton, where N-lauroyl salicylhydrazide (H3lshz) was used as the primary building unit to generate the helical tecton as a secondary building unit. While the 41/43 screw symmetry-linked helical coordination network was obtained when the primary building units had an N-acetyl group, both the 31/32 screw symmetry-linked and the 41/43 screw symmetry-linked helical coordination networks were obtained simultaneously in the same batch when the primary building unit had a long alkyl N-lauroyl group at the N-acetyl site.
Publisher
AMER CHEMICAL SOC
ISSN
0020-1669

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