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DC Field | Value | Language |
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dc.citation.endPage | 2803 | - |
dc.citation.number | 8 | - |
dc.citation.startPage | 2794 | - |
dc.citation.title | MACROMOLECULES | - |
dc.citation.volume | 39 | - |
dc.contributor.author | Baek, Jong-Beom | - |
dc.contributor.author | Tan, LS | - |
dc.date.accessioned | 2023-12-22T10:07:19Z | - |
dc.date.available | 2023-12-22T10:07:19Z | - |
dc.date.created | 2014-09-16 | - |
dc.date.issued | 2006-04 | - |
dc.description.abstract | A new self-polymerizable AB 2 monomer, 2,3-bis(4-phenoxyphenyl) quinoxaline-6-carboxylic acid, was synthesized from the double condensation reaction of 4,4'-diphenoxybenzil and 3,4-diaminobenzoic acid. It was polymerized to afford the corresponding hyperbranched poly(phenylquinoxaline) (PPQ) via a diaryl ketone formation from the Friedel-Crafts reaction of the carboxylic acid group (A) and the phenoxy ring (B) in polyphosphoric acid (PPA)/P 2O 5 medium. The polymerization was conducted at (i) 130 and 160 °C and (ii) with and without additional amounts of P 2O 5 and monitored by analyzing the polymerization mixture sampled at certain reaction temperature and time intervals with Fourier transform infrared (FT-IR) spectroscopy and gelpermeation chromatography (GPC). Both FT-IR and GPC results corroborated our previously established optimal conditions: (i) PPA:P 2O 5 ratio of 4:1 and (ii) efficient polymerization temperature ∼130 °C. Furthermore, the series of 10 aliquots taken from the mixture prepared under the optimal conditions, precipitated into water, and stored in the vials for a month showed visually a consistent trend and a transition in the polymer densities and collectively allowed the visualization of a changeover in the macromolecular architecture from a "fanlike" conformation at the early stage of polymerization to a denser, globular conformation at higher molecular weights. The resultant hyperbranched PPQ was thermally stable with 5% weight loss at temperatures over 500 °C in both air and helium atmospheres. It showed UV absorption maxima at 365-370 nm and emission maxima at 433-446 nm. The subsequent chain-end functionality conversion for the parent hyperbranched polymer could be performed in either a one-pot fashion or a two-staged process. Finally, some anomalous dilute-solution behavior (negative or "inverse" polyelectrolyte effect) was observed for the chain-end-modified hyperbranched polymers that appeared to be significantly influenced by the nature of solvents (acidic vs basic) and chain-end groups (polarity). | - |
dc.identifier.bibliographicCitation | MACROMOLECULES, v.39, no.8, pp.2794 - 2803 | - |
dc.identifier.doi | 10.1021/ma0526589 | - |
dc.identifier.issn | 0024-9297 | - |
dc.identifier.scopusid | 2-s2.0-33646051210 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/6049 | - |
dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=33646051210 | - |
dc.identifier.wosid | 000236996200013 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Hyperbranched poly(phenylquinoxaline-ether-ketone) synthesis in poly(phosphoric acid)/P2O5 medium: Optimization and some interesting observations | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | POLY(ARYL ETHER PHENYLQUINOXALINES) | - |
dc.subject.keywordPlus | POLYMERIZABLE QUINOXALINE MONOMERS | - |
dc.subject.keywordPlus | MULTIWALLED CARBON NANOTUBES | - |
dc.subject.keywordPlus | MAIN-CHAIN | - |
dc.subject.keywordPlus | POLYPHOSPHORIC ACID/P2O5 | - |
dc.subject.keywordPlus | AROMATIC POLYAMIDES | - |
dc.subject.keywordPlus | ACID | - |
dc.subject.keywordPlus | UNITS | - |
dc.subject.keywordPlus | NANOFIBERS | - |
dc.subject.keywordPlus | RINGS | - |
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