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신현석

Shin, Hyeon Suk
Lab for Carbon and 2D Materials
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New approach to generalized two-dimensional correlation spectroscopy. 1: Combination of principal component analysis and two-dimensional correlation spectroscopy

Author(s)
Jung, YMShin, Hyeon SukBin Kim, SNoda, I
Issued Date
2002-12
DOI
10.1366/000370202321116020
URI
https://scholarworks.unist.ac.kr/handle/201301/5820
Fulltext
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=0036966223
Citation
APPLIED SPECTROSCOPY, v.56, no.12, pp.1562 - 1567
Abstract
The direct combination of chemometrics and two-dimensional (2D) correlation spectroscopy is considered. The use of a reconstructed data matrix based on the significant scores and loading vectors obtained from the principal component analysis (PCA) of raw spectral data is proposed as a method to improve the data quality for 2D correlation analysis. The synthetic noisy spectra were analyzed to explore the novel possibility of the use of PCA-reconstructed spectra, which are highly noise suppressed, 2D correlation analysis of this reconstructed data matrix, instead of the raw data matrix, can significantly reduce the contribution of the noise component to the resulting 2D correlation spectra.
Publisher
SOC APPLIED SPECTROSCOPY
ISSN
0003-7028

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