BROWSE

Related Researcher

Author

Lah, Myoung Soo
Nanoporous Materials Lab
Research Interests
  • Metal-Organic Frameworks (MOFs)

ITEM VIEW & DOWNLOAD

2D Layered metal–organic frameworks built using a hexanuclear metallamacrocycle and an octanuclear metallamacrocycle as supramolecular building blocks

Cited 14 times inthomson ciCited 12 times inthomson ci
Title
2D Layered metal–organic frameworks built using a hexanuclear metallamacrocycle and an octanuclear metallamacrocycle as supramolecular building blocks
Author
Moon, DohyunSong, JihehLah, Myoung Soo
Keywords
COORDINATION POLYMERS; MANGANESE METALLADIAZAMACROCYCLE; 2-DIMENSIONAL NETWORK; STERIC CONTROL; UNITS; DESIGN; NUCLEARITY; CRYSTALS; CAVITIES; COMPLEX
Issue Date
2009
Publisher
ROYAL SOC CHEMISTRY
Citation
CRYSTENGCOMM, v.11, no.5, pp.770 - 776
Abstract
Two different 2D layered metal-organic frameworks (MOFs) have been prepared using a hexanuclear manganese metallamacrocycle and an octanuclear manganese metallamacrocycle as supramolecular building blocks via a simple change of the solvent used and/or addition of a templating agent. While the sheets in the 2D MOF [Mn(6)(pshz)(6)(bpea)(2)(dma)(2)](n), 2 (where, pshz(3-) is N-propionylsalicylhydrazidate, bpea is 1,2-bis(pyridyl)ethane, and dma is N,N-dimethylacetamide), built based on a hexanuclear metalladiazamacrocycle are in a staggered orientation, the sheets in the 2D MOF [Mn(8)(pshz)(8)(bpea)(2)(dma)(4)](n), 3, built based on an octanuclear metalladiazamacrocycle are in an eclipsed orientation. However, both MOFs have the same 3-connected 4.8(2) network topology.
URI
Go to Link
DOI
http://dx.doi.org/10.1039/b813603c
ISSN
1466-8033
Appears in Collections:
SNS_Journal Papers

find_unist can give you direct access to the published full text of this article. (UNISTARs only)

Show full item record

qr_code

  • mendeley

    citeulike

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

MENU