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Oh, Hyunchul
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A Cryogenically Flexible Covalent Organic Framework for Efficient Hydrogen Isotope Separation by Quantum Sieving

Author(s)
Oh, HyunchulKalidindi, Suresh BabuUm, YoungjeBureekaew, SareeyaSchmid, RochusFischer, Roland A.Hirscher, Michael
Issued Date
2013-12
DOI
10.1002/anie.201307443
URI
https://scholarworks.unist.ac.kr/handle/201301/57856
Fulltext
https://onlinelibrary.wiley.com/doi/10.1002/anie.201307443
Citation
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.52, no.50, pp.13219 - 13222
Abstract
The physical upper limit of hydrogen uptake for powder and compressed pellet MIL-101 has been experimentally investigated. Maximum uptake in pellets at 20 K achieves 9.6 wt% and 42 g L−1. Moreover, cryo-adsorption of hydrogen on pellets compared to liquid H2 possesses a larger temperature window for operation without boil-off loss, which will be beneficial for industrial applications.
Publisher
WILEY-V C H VERLAG GMBH
ISSN
1433-7851
Keyword (Author)
covalent organic frameworksgas adsorptionhydrogen isotopesisotope separationquantum sieving
Keyword
H-2D-2DESORPTIONADSORPTION

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