dc.citation.endPage |
9163 |
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dc.citation.number |
26 |
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dc.citation.startPage |
9162 |
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dc.citation.title |
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY |
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dc.citation.volume |
131 |
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dc.contributor.author |
Rohde, Jan-Uwe |
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dc.contributor.author |
Lee, Wei-Tsung |
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dc.date.accessioned |
2023-12-22T07:44:29Z |
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dc.date.available |
2023-12-22T07:44:29Z |
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dc.date.created |
2014-08-28 |
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dc.date.issued |
2009-07 |
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dc.description.abstract |
Electron-rich tris(guanidinato) complexes of IrIII, [Ir{ArNC(NR2)NAr}3] (where R = Me or Et; Ar = Ph or 4-MeC6H4), were synthesized from the respective [Ir{ArNC(NR2)NAr}(C8H14) 2] precursors (C8H14 = cis-cyclooctene), are air-sensitive, and can be electrochemically oxidized in two one-electron transfer steps. The first electron transfer is reversible and occurs at much lower potentials than typical for IrIII. Chemical oxidation by [FeCp2]PF6 afforded isolable, paramagnetic IrIV compounds, [Ir{ArNC(NR2)NAr}3]PF6, which were characterized by analytical and spectroscopic methods and a single-crystal structure determination, demonstrating that IrIV is accessible in a nitrogen-donor ligand environment. |
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dc.identifier.bibliographicCitation |
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.131, no.26, pp.9162 - 9163 |
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dc.identifier.doi |
10.1021/ja9033445 |
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dc.identifier.issn |
0002-7863 |
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dc.identifier.scopusid |
2-s2.0-67649980010 |
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dc.identifier.uri |
https://scholarworks.unist.ac.kr/handle/201301/5733 |
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dc.identifier.url |
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=67649980010 |
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dc.identifier.wosid |
000267633300015 |
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dc.language |
영어 |
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dc.publisher |
AMER CHEMICAL SOC |
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dc.title |
Stabilization of Iridium(IV) by Monoanionic Dialkyldiarylguanidinato Ligands |
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dc.type |
Article |
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dc.description.journalRegisteredClass |
scopus |
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