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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 5380 | - |
dc.citation.number | 22 | - |
dc.citation.startPage | 5376 | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 51 | - |
dc.contributor.author | Braymer, Joseph J. | - |
dc.contributor.author | O'Neill, Kevin P. | - |
dc.contributor.author | Rohde, Jan-Uwe | - |
dc.contributor.author | Lim, Mi Hee | - |
dc.date.accessioned | 2023-12-22T05:09:52Z | - |
dc.date.available | 2023-12-22T05:09:52Z | - |
dc.date.created | 2014-08-28 | - |
dc.date.issued | 2012-05 | - |
dc.description.abstract | An Fe IV=O group meets with H 2O 2! Reaction of high-valent iron with the reactive oxygen species (ROS) hydrogen peroxide (H 2O 2) is in general reserved for heme centers. Employing a biomimetic metal complex, the direct reaction of a mononuclear nonheme oxoiron(IV) species with H 2O 2 was observed and studied mechanistically, offering a new perspective for the chemistry between ROS and high-valent oxometal complexes | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.51, no.22, pp.5376 - 5380 | - |
dc.identifier.doi | 10.1002/anie.201200901 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.scopusid | 2-s2.0-84861501411 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/5728 | - |
dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84861501411 | - |
dc.identifier.wosid | 000304345800018 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | The Reaction of a High-Valent Nonheme Oxoiron(IV) Intermediate with Hydrogen Peroxide | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | bioinorganic chemistry | - |
dc.subject.keywordAuthor | enzyme models | - |
dc.subject.keywordAuthor | iron | - |
dc.subject.keywordAuthor | reaction mechanisms | - |
dc.subject.keywordAuthor | reactive oxygen species | - |
dc.subject.keywordPlus | CYCLOOCTENE EPOXIDATION | - |
dc.subject.keywordPlus | ATOM TRANSFER | - |
dc.subject.keywordPlus | MYCOBACTERIUM-TUBERCULOSIS | - |
dc.subject.keywordPlus | CHEMICAL-PROPERTIES | - |
dc.subject.keywordPlus | OXYGEN ACTIVATION | - |
dc.subject.keywordPlus | CATALASE ACTIVITY | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | IRON ENZYMES | - |
dc.subject.keywordPlus | FERRYL ION | - |
dc.subject.keywordPlus | COMPLEXES | - |
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