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Rohde, Jan-Uwe
Transition Metal Chemistry
Research Interests
  • Inorganic chemistry, coordination chemistry, organometallic chemistry, chemical synthesis, catalysis, green chemistry, inorganic reaction mechanisms.

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The Reaction of a High-Valent Nonheme Oxoiron(IV) Intermediate with Hydrogen Peroxide

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Title
The Reaction of a High-Valent Nonheme Oxoiron(IV) Intermediate with Hydrogen Peroxide
Author
Braymer, Joseph J.O'Neill, Kevin P.Rohde, Jan-UweLim, Mi Hee
Keywords
bioinorganic chemistry; enzyme models; iron; reaction mechanisms; reactive oxygen species
Issue Date
201205
Publisher
WILEY-V C H VERLAG GMBH
Citation
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.51, no.22, pp.5376 - 5380
Abstract
An Fe IV=O group meets with H 2O 2! Reaction of high-valent iron with the reactive oxygen species (ROS) hydrogen peroxide (H 2O 2) is in general reserved for heme centers. Employing a biomimetic metal complex, the direct reaction of a mononuclear nonheme oxoiron(IV) species with H 2O 2 was observed and studied mechanistically, offering a new perspective for the chemistry between ROS and high-valent oxometal complexes
URI
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DOI
http://dx.doi.org/10.1002/anie.201200901
ISSN
1433-7851
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