BROWSE

Related Researcher

Author

Rohde, Jan-Uwe
Transition Metal Chemistry
Research Interests
  • Inorganic chemistry, coordination chemistry, organometallic chemistry, chemical synthesis, catalysis, green chemistry, inorganic reaction mechanisms.

ITEM VIEW & DOWNLOAD

Evidence for a reactive (alkene)peroxoiridium(III) intermediate in the oxidation of an alkene complex with O2

Cited 7 times inthomson ciCited 7 times inthomson ci
Title
Evidence for a reactive (alkene)peroxoiridium(III) intermediate in the oxidation of an alkene complex with O2
Author
Kelley, Matthew R.Rohde, Jan-Uwe
Keywords
TRANSITION-METAL COMPLEXES; MOLECULAR-OXYGEN; ORGANOMETALLIC CHEMISTRY; CATALYZED OXIDATION; SELECTIVE OXIDATION; TERMINAL OLEFINS; DIOXYGEN; MECHANISM; RHODIUM; EPOXIDATION
Issue Date
201203
Publisher
ROYAL SOC CHEMISTRY
Citation
CHEMICAL COMMUNICATIONS, v.48, no.23, pp.2876 - 2878
Abstract
An (alkene)peroxoiridium(iii) complex, [Ir(L)(cod)(O 2)] [where LH = PhNC(NMe 2)NHPh and cod = 1,5-cyclooctadiene], was identified as an intermediate in the reaction of the Ir I precursor [Ir(L)(cod)] with O 2 and characterized by spectroscopic methods. Decay of the intermediate and further reaction with 1,5-cyclooctadiene produced 4-cycloocten-1-one
URI
Go to Link
DOI
http://dx.doi.org/10.1039/c2cc17332h
ISSN
1359-7345
Appears in Collections:
SNS_Journal Papers

find_unist can give you direct access to the published full text of this article. (UNISTARs only)

Show full item record

qr_code

  • mendeley

    citeulike

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

MENU