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Author

Lah, Myoung Soo
Nanoporous Materials Lab
Research Interests
  • Metal-Organic Frameworks (MOFs)

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THE TETRANUCLEAR CLUSTER FEIII[FEIII(SALICYLHYDROXIMATO)(MEOH)(ACETATE)]3 IS AN ANALOG OF M3+(9-CROWN-3)

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Title
THE TETRANUCLEAR CLUSTER FEIII[FEIII(SALICYLHYDROXIMATO)(MEOH)(ACETATE)]3 IS AN ANALOG OF M3+(9-CROWN-3)
Author
Lah, Myoung SooKIRK, MLHATFIELD, WPECORARO, VL
Issue Date
198911
Publisher
Royal Society of Chemistry
Citation
JOURNAL OF THE CHEMICAL SOCIETY - SERIES CHEMICAL COMMUNICATIONS, v., no.21, pp.1606 - 1608
Abstract
The first example of transition metal co-ordination to ethereal like oxygens of a 9-metallocrown-3 ether is seen in FeIII[Fe III(salicylhydroximato)(MeOH)(acetate)]3 and leads to an unusual tetranuclear cluster which exhibits both inter- and intra-cluster antiferromagnetic interactions and an S = 5 ground state.
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DOI
http://dx.doi.org/10.1039/c39890001606
ISSN
0022-4936
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