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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 5470 | - |
dc.citation.number | 35 | - |
dc.citation.startPage | 5465 | - |
dc.citation.title | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | - |
dc.contributor.author | Choi, Jeungwook | - |
dc.contributor.author | Park, Jaejoon | - |
dc.contributor.author | Park, Mira | - |
dc.contributor.author | Moon, Dohyun | - |
dc.contributor.author | Lah, Myoung Soo | - |
dc.date.accessioned | 2023-12-22T08:14:55Z | - |
dc.date.available | 2023-12-22T08:14:55Z | - |
dc.date.created | 2014-09-01 | - |
dc.date.issued | 2008-12 | - |
dc.description.abstract | The hexanuclear manganese metallamacrocycle [Mn(6)-(Haahz)(6)(dmso)(6)] (1) was prepared by using a new pentadentate ligand, N-acetylaminobenzhydrazide (H(4)aahz), and a manganese ion as primary building blocks in dimethyl sulfoxide (dmso). Under identical conditions but. in the presence of 1,2-bis(4-pyridyl)ethane (bpea) as an exo-bidentate linker in dimethylformamide (dmf), the 2D layered metal-organic framework (MOF) [Mn(6)(Haahz)(6)(bpea)(2)(dmf)(2)](n) (2) was obtained, where the hexam-1clear manganese metallamacrocycle served as a supramolecular building block. The network topology of 2, a 3-connected 4.8(2) topology, is quite different, from those of the MOFs obtained from a similar pentadentate ligand, N-acylsalicylhydrazide, although the same hexanuclear manganese metallamacrocycles were used as supra-molecular building blocks and bpea was used as the same linker ligand. Although the layers of 2 are staggered relative to each other, the network has quite a large solvent cavity between the layers, because of the corrugated nature of the layer. | - |
dc.identifier.bibliographicCitation | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, no.35, pp.5465 - 5470 | - |
dc.identifier.doi | 10.1002/ejic.200800665 | - |
dc.identifier.issn | 1434-1948 | - |
dc.identifier.scopusid | 2-s2.0-57149091562 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/5580 | - |
dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=57149091562 | - |
dc.identifier.wosid | 000261941000004 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | A 2D Layered Metal-Organic Framework Constructed by Using a Hexanuclear Manganese Metallamacrocycle as a Supramolecular Building Block | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | Metallacycles | - |
dc.subject.keywordAuthor | Macrocycles | - |
dc.subject.keywordAuthor | Supramolecular chemistry | - |
dc.subject.keywordAuthor | Metal-organic frameworks | - |
dc.subject.keywordAuthor | Layered compounds | - |
dc.subject.keywordPlus | 2-DIMENSIONAL NETWORK | - |
dc.subject.keywordPlus | MOLECULAR-SIEVE | - |
dc.subject.keywordPlus | STERIC CONTROL | - |
dc.subject.keywordPlus | DESIGN | - |
dc.subject.keywordPlus | OCTANUCLEAR | - |
dc.subject.keywordPlus | UNITS | - |
dc.subject.keywordPlus | SIZE | - |
dc.subject.keywordPlus | METALLADIAZAMACROCYCLE | - |
dc.subject.keywordPlus | ADSORPTION | - |
dc.subject.keywordPlus | NUCLEARITY | - |
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