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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 6583 | - |
dc.citation.number | 46 | - |
dc.citation.startPage | 6579 | - |
dc.citation.title | DALTON TRANSACTIONS | - |
dc.contributor.author | Liu, Xinfang | - |
dc.contributor.author | Liu, Wenlong | - |
dc.contributor.author | Lee, Kyungjin | - |
dc.contributor.author | Park, Mira | - |
dc.contributor.author | Ri, Hyeong-Cheol | - |
dc.contributor.author | Kim, Ghyung Hwa | - |
dc.contributor.author | Lah, Myoung Soo | - |
dc.date.accessioned | 2023-12-22T09:06:58Z | - |
dc.date.available | 2023-12-22T09:06:58Z | - |
dc.date.created | 2014-09-01 | - |
dc.date.issued | 2008 | - |
dc.description.abstract | The reaction of Mn(OAc)2·4H2O with 2,6-dimethoxybenzoylsalicylhydrazide (H3dmbshz) leads to a dodecanuclear manganese metallamacrocycle [Mn12(dmbshz) 12(EtOH)6], 1. The successive manganese centers are connected by the hydrazide N-N groups of the ligands in an alternating pentadentate binding mode, hexadentate binding mode. The alternation results in two alternating chelation modes around the metal centers, a tridentate- tridentate chelation mode and a bidentate-tridentate chelation mode. The metal ions in 1 are in a ⋯(AAΔBC AΛB)(AAΔBC AΛB)⋯ chiral sequence, the alternation of the chiralities expanding the cyclic ring system to a 36-membered dodecanuclear manganese metallamacrocyclic ring system with S6 point group symmetry. | - |
dc.identifier.bibliographicCitation | DALTON TRANSACTIONS, no.46, pp.6579 - 6583 | - |
dc.identifier.doi | 10.1039/b810711d | - |
dc.identifier.issn | 1477-9226 | - |
dc.identifier.scopusid | 2-s2.0-56849095495 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/5553 | - |
dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=56849095495 | - |
dc.identifier.wosid | 000261742700012 | - |
dc.language | 영어 | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | A dodecanuclear metallamacrocycle having a multidentate bridging ligand in two different binding modes | - |
dc.type | Article | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | MANGANESE METALLADIAZAMACROCYCLE | - |
dc.subject.keywordPlus | SUPRAMOLECULAR ISOMERISM | - |
dc.subject.keywordPlus | COORDINATION CHEMISTRY | - |
dc.subject.keywordPlus | STERIC CONTROL | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | HEXANUCLEAR | - |
dc.subject.keywordPlus | NUCLEARITY | - |
dc.subject.keywordPlus | 18-METALLACROWN-6 | - |
dc.subject.keywordPlus | OCTANUCLEAR | - |
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