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Shin, Hyung-Joon
Nanoscale Materials Science Lab (NMSL)
Research Interests
  • Scanning tunneling microscopy, surface science, interface science, nanomaterials

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Combined Scanning Tunneling Microscopy and High-Resolution Electron Energy Loss Spectroscopy Study on the Adsorption State of CO on Ag(001)

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Title
Combined Scanning Tunneling Microscopy and High-Resolution Electron Energy Loss Spectroscopy Study on the Adsorption State of CO on Ag(001)
Author
Arafune, RyuichiShin, Hyung-JoonJung, JaehoonMinamitani, EmiTakagi, NoriakiKim, YousooKawai, Maki
Keywords
Adsorption site; Adsorption state; Atop sites; CO molecule; Gasphase; High resolution electron energy loss spectroscopy; Inelastic electron tunneling spectroscopy; Scanning tunneling microscopes; Stretching modes; Vibrational energies
Issue Date
201209
Publisher
AMER CHEMICAL SOC
Citation
LANGMUIR, v.28, no.37, pp.13249 - 13252
Abstract
The adsorption site and vibrational energies of CO on a clean Ag(001) surface were determined using scanning tunneling microscopy, inelastic electron tunneling spectroscopy with a scanning tunneling microscope, and high-resolution electron energy loss spectroscopy. The CO molecules were found to adsorb on the atop site of the Ag(001) surface, which was similar to their adsorption on the Cu(001) surface. The vibrational energy of the CO internal stretching mode was found to be 263 meV, which is only 3 meV less than that of CO in the gas phase. This result indicates that the CO molecules chemisorb very weakly on the Ag(001) surface.
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DOI
http://dx.doi.org/10.1021/la3024088
ISSN
0743-7463
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