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DC Field | Value | Language |
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dc.citation.endPage | 6172 | - |
dc.citation.number | 16 | - |
dc.citation.startPage | 6141 | - |
dc.citation.title | CHEMICAL SOCIETY REVIEWS | - |
dc.citation.volume | 43 | - |
dc.contributor.author | Guillerm, Vincent | - |
dc.contributor.author | Kim, Dongwook | - |
dc.contributor.author | Eubank, Jarrod F. | - |
dc.contributor.author | Luebke, Ryan | - |
dc.contributor.author | Liu, Xinfang | - |
dc.contributor.author | Adil, Karim | - |
dc.contributor.author | Lah, Myoung Soo | - |
dc.contributor.author | Eddaoudi, Mohamed | - |
dc.date.accessioned | 2023-12-22T02:17:23Z | - |
dc.date.available | 2023-12-22T02:17:23Z | - |
dc.date.created | 2014-08-20 | - |
dc.date.issued | 2014-08 | - |
dc.description.abstract | In this review, we describe two recently implemented conceptual approaches facilitating the design and deliberate construction of metal-organic frameworks (MOFs), namely supermolecular building block (SBB) and supermolecular building layer (SBL) approaches. Our main objective is to offer an appropriate means to assist/aid chemists and material designers alike to rationally construct desired functional MOF materials, made-to-order MOFs. We introduce the concept of net-coded building units (net-cBUs), where precise embedded geometrical information codes uniquely and matchlessly a selected net, as a compelling route for the rational design of MOFs. This concept is based on employing pre-selected 0-periodic metal-organic polyhedra or 2-periodic metal-organic layers, SBBs or SBLs respectively, as a pathway to access the requisite net-cBUs. In this review, inspired by our success with the original rht-MOF, we extrapolated our strategy to other known MOFs via their deconstruction into more elaborate building units (namely polyhedra or layers) to (i) elucidate the unique relationship between edge-transitive polyhedra or layers and minimal edge-transitive 3-periodic nets, and (ii) illustrate the potential of the SBB and SBL approaches as a rational pathway for the design and construction of 3-periodic MOFs. Using this design strategy, we have also identified several new hypothetical MOFs which are synthetically targetable. | - |
dc.identifier.bibliographicCitation | CHEMICAL SOCIETY REVIEWS, v.43, no.16, pp.6141 - 6172 | - |
dc.identifier.doi | 10.1039/c4cs00135d | - |
dc.identifier.issn | 0306-0012 | - |
dc.identifier.scopusid | 2-s2.0-84904765810 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/5492 | - |
dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84904765810 | - |
dc.identifier.wosid | 000340514600031 | - |
dc.language | 영어 | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | A supermolecular building approach for the design and construction of metal-organic frameworks | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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