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- Ruoff, Rodney S.
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STABILITY OF FULLERENE-BASED SYSTEMS
- Author(s)
- TOMANEK, D, WANG, Y, RUOFF, RS
- Issued Date
- 1993-12
- Citation
- JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, v.54, no.12, pp.1679 - 1684
- Abstract
- Chemical modification of fullerenes such as the C60 molecule is a promising way to generate novel materials with tailored properties. Exohedral insertion of atoms in the interstitial sites of the C60 solid has created a new class of superconductors. Encapsulation of atoms in the fullerene cage is expected to lead to stable M@C60 endohedral complexes with a very interesting optical response. We study the stability of MxC60 solids and M@C60 molecules using a Born-Haber cycle. Our analysis not only provides the formations energies, but also elucidates the stability trends across the periodic table.
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- ISSN
- 0022-3697
- Keyword (Author)
- C60, C60 ENDOHEDRAL COMPLEXES OF, C60-INTERCALATION COMPOUNDS OF FORMATION ENTHALPY, SUPERCONDUCTIVITY
- Keyword
- ELECTRONIC-PROPERTIES, SUPERCONDUCTIVITY, C-60, C60, CARBON
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