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Chlorination of Reduced Graphene Oxide Enhances the Dielectric Constant of Reduced Graphene Oxide/Polymer Composites

Author(s)
Kim, Jin-YoungLee, Wi HyoungSuk, Ji WonPotts, Jeffrey R.Chou, HarryKholmanov, Iskandar N.Piner, Richard D.Lee, JonghoAkinwande, DejiRuoff, Rodney S.
Issued Date
2013-04
DOI
10.1002/adma.201300385
URI
https://scholarworks.unist.ac.kr/handle/201301/54219
Fulltext
https://onlinelibrary.wiley.com/doi/10.1002/adma.201300385
Citation
ADVANCED MATERIALS, v.25, no.16, pp.2308 - 2313
Abstract
Phenyl isocyanate-functionalized and hydrazine-reduced reduced graphene oxide (rG-O) is treated to produce chlorinated rG-O (Cl-rG-O) platelets. The dielectric constant of the composite film containing Cl-rG-O shows a 5.5-fold increase over that of composites of untreated rG-O and this cyanoethyl-based polymer, a consequence of the combination of polar and polarizable C-Cl bonds and the increased interfacial polarization.
Publisher
WILEY-V C H VERLAG GMBH
ISSN
0935-9648
Keyword (Author)
reduced graphene oxidechlorinationpolymerscomposite filmsdielectric performance
Keyword
CARBON NANOTUBESFILMSGRAPHITETRANSPARENTCONDUCTIVITYPERSPECTIVESDEPENDENCEREDUCTIONFREQUENCYBEHAVIOR

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