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Cho, Jaeheung
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Isolation and structural characterization of the elusive 1:1 adduct of hydrazine and carbon dioxide

Author(s)
Lee, ByeongnoKang, Seung HeeKang, DonghyeonLee, Kyu HyungCho, JaeheungNam, WonwooHan, Oc HeeHur, Nam Hwi
Issued Date
2011-10
DOI
10.1039/c1cc14542h
URI
https://scholarworks.unist.ac.kr/handle/201301/48145
Fulltext
https://pubs.rsc.org/en/content/articlelanding/2011/CC/c1cc14542h#!divAbstract
Citation
CHEMICAL COMMUNICATIONS, v.47, no.40, pp.11219 - 11221
Abstract
A solid hydrazine was isolated as a crystalline powder by reacting aqueous hydrazine with supercritical CO2. Its structure determined by single crystal X-ray diffraction shows a zwitterionic form of NH3+NHCO2-. The solid hydrazine is remarkably stable but is as reactive as liquid hydrazine even in the absence of solvents.
Publisher
ROYAL SOC CHEMISTRY
ISSN
1359-7345
Keyword
STATE NMR-SPECTROSCOPYSOLID-STATENEUTRON-DIFFRACTIONCHEMICAL-SHIFTSEMISSIONCRYSTALGLYCINEAZINESAMMONIAACID

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