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DC Field | Value | Language |
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dc.citation.endPage | 11879 | - |
dc.citation.number | 31 | - |
dc.citation.startPage | 11876 | - |
dc.citation.title | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | - |
dc.citation.volume | 133 | - |
dc.contributor.author | Hong, Seungwoo | - |
dc.contributor.author | Lee, Yong-Min | - |
dc.contributor.author | Cho, Kyung-Bin | - |
dc.contributor.author | Sundaravel, Karuppasamy | - |
dc.contributor.author | Cho, Jaeheung | - |
dc.contributor.author | Kirn, Myoung Jin | - |
dc.contributor.author | Shin, Woonsup | - |
dc.contributor.author | Nam, Wonwoo | - |
dc.date.accessioned | 2023-12-22T06:06:25Z | - |
dc.date.available | 2023-12-22T06:06:25Z | - |
dc.date.created | 2020-09-01 | - |
dc.date.issued | 2011-08 | - |
dc.description.abstract | Mononuclear nonheme iron(IV)-oxo complexes with two different topologies, cis-α-[FeIV(O)(BQCN)]2+ and cis-β-[FeIV(O)(BQCN)]2+, were synthesized and characterized with various spectroscopic methods. The effect of ligand topology on the reactivities of nonheme iron(IV)-oxo complexes was investigated in C–H bond activation and oxygen atom-transfer reactions; cis-α-[FeIV(O)(BQCN)]2+ was more reactive than cis-β-[FeIV(O)(BQCN)]2+ in the oxidation reactions. The reactivity difference between the cis-α and cis-β isomers of [FeIV(O)(BQCN)]2+ was rationalized with the FeIV/III redox potentials of the iron(IV)-oxo complexes: the FeIV/III redox potential of the cis-α isomer was 0.11 V higher than that of the cis-β isomer. | - |
dc.identifier.bibliographicCitation | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.133, no.31, pp.11876 - 11879 | - |
dc.identifier.doi | 10.1021/ja204008u | - |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.scopusid | 2-s2.0-79961131345 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/48140 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/ja204008u | - |
dc.identifier.wosid | 000293768400017 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Ligand Topology Effect on the Reactivity of a Mononuclear Nonheme Iron(IV)-Oxo Complex in Oxygenation Reactions | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | ELECTRON-TRANSFER PROPERTIES | - |
dc.subject.keywordPlus | SPIN OXOIRON(IV) COMPLEX | - |
dc.subject.keywordPlus | SPECTROSCOPIC CHARACTERIZATION | - |
dc.subject.keywordPlus | OXIDATION CATALYSIS | - |
dc.subject.keywordPlus | CORRELATION-ENERGY | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | DENSITY | - |
dc.subject.keywordPlus | EXCHANGE | - |
dc.subject.keywordPlus | OXO | - |
dc.subject.keywordPlus | IRON(II) | - |
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