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Cho, Jaeheung
BIOCC at UNIST
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dc.citation.endPage 9331 -
dc.citation.number 67 -
dc.citation.startPage 9328 -
dc.citation.title CHEMICAL COMMUNICATIONS -
dc.citation.volume 53 -
dc.contributor.author Kim, Bohee -
dc.contributor.author Jeong, Donghyun -
dc.contributor.author Cho, Jaeheung -
dc.date.accessioned 2023-12-21T21:49:13Z -
dc.date.available 2023-12-21T21:49:13Z -
dc.date.created 2020-09-03 -
dc.date.issued 2017-08 -
dc.description.abstract Copper(II)-alkylperoxo adducts, [Cu(CHDAP)(OOR)](+) (CHDAP = N, N'-dicyclohexyl-2,11-diaza[3,3](2,6)pyridinophane; R = C(CH3)(2)Ph and tBu), were prepared and characterized using various physicochemical methods. These are the first synthetic Cu(II)-alkylperoxo complexes that can perform aldehyde deformylation (i.e., nucleophilic reactivity) under the stoichiometric reaction conditions, which was confirmed by kinetic studies. -
dc.identifier.bibliographicCitation CHEMICAL COMMUNICATIONS, v.53, no.67, pp.9328 - 9331 -
dc.identifier.doi 10.1039/c7cc03965d -
dc.identifier.issn 1359-7345 -
dc.identifier.scopusid 2-s2.0-85027550211 -
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/48106 -
dc.identifier.url https://pubs.rsc.org/en/content/articlelanding/2017/CC/C7CC03965D#!divAbstract -
dc.identifier.wosid 000407808000009 -
dc.language 영어 -
dc.publisher ROYAL SOC CHEMISTRY -
dc.title Nucleophilic reactivity of copper(II)-alkylperoxo complexes -
dc.type Article -
dc.description.isOpenAccess FALSE -
dc.relation.journalWebOfScienceCategory Chemistry, Multidisciplinary -
dc.relation.journalResearchArea Chemistry -
dc.type.docType Article -
dc.description.journalRegisteredClass scie -
dc.description.journalRegisteredClass scopus -
dc.subject.keywordPlus III-OOR COMPLEXES -
dc.subject.keywordPlus O BOND-CLEAVAGE -
dc.subject.keywordPlus HIGH-SPIN IRON(III)-ALKYLPEROXO -
dc.subject.keywordPlus NONHEME IRON MODELS -
dc.subject.keywordPlus SUPEROXIDE REDUCTASE -
dc.subject.keywordPlus ELECTRONIC-STRUCTURE -
dc.subject.keywordPlus COORDINATION SPHERE -
dc.subject.keywordPlus OXIDATION -
dc.subject.keywordPlus ACTIVATION -
dc.subject.keywordPlus MECHANISM -

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