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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 1140 | - |
dc.citation.number | 6 | - |
dc.citation.startPage | 1134 | - |
dc.citation.title | ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | - |
dc.citation.volume | 640 | - |
dc.contributor.author | Santra, Atanu | - |
dc.contributor.author | Lah, Myoung Soo | - |
dc.contributor.author | Bharadwaj, Parimal K. | - |
dc.date.accessioned | 2023-12-22T02:41:17Z | - |
dc.date.available | 2023-12-22T02:41:17Z | - |
dc.date.created | 2014-05-29 | - |
dc.date.issued | 2014-05 | - |
dc.description.abstract | The hydrothermal reaction of Zn(NO3)2·H 2O and a linear 2, 2'-bis-trifluoromethyl-biphenyl-4, 4'-dicarboxylic acid (H2L) ligand with-CF3 groups at each phenyl moiety of the biphenyl rings leads to the formation of a three-fold interpenetrated metal-organic framework (MOF), {[Zn2.66O0.66(L) 2]·2H2O}n (1) at 180 °C. Single-crystal X-ray diffraction studies revealed that 1 is constructed from polynuclear clusters [Zn4O(COO)6] as secondary building units (SBU). These SBU are connected through the L2- to generate an overall three-dimensional structure with a 6-connected primitive cuboidal (α-Po) network. Thermogravimetric analyses and variable temperature powder X-ray diffraction measurements suggested that 1 is thermally stable. The porosity of 1 was estimated by N2, CO2, H2, and CH4 at different temperatures. The framework showed high selectivity of CO2 uptake over N2 and CH4. Furthermore, solid-state photoluminescence studies were carried out for complex 1 upon excitation at 275 nm at room temperature. | - |
dc.identifier.bibliographicCitation | ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, v.640, no.6, pp.1134 - 1140 | - |
dc.identifier.doi | 10.1002/zaac.201300639 | - |
dc.identifier.issn | 0044-2313 | - |
dc.identifier.scopusid | 2-s2.0-84900871781 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/4804 | - |
dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84900871781 | - |
dc.identifier.wosid | 000335973100018 | - |
dc.language | 영어 | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.title | A Partially Fluorinated Three-fold Interpenetrated Stable Metal- Organic Framework with Selective CO2 Uptake | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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