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dc.citation.endPage 968 -
dc.citation.number 5047 -
dc.citation.startPage 966 -
dc.citation.title SCIENCE -
dc.citation.volume 255 -
dc.contributor.author JOHNSON, HE -
dc.contributor.author GRANICK, S -
dc.date.accessioned 2023-12-22T13:07:38Z -
dc.date.available 2023-12-22T13:07:38Z -
dc.date.created 2020-08-05 -
dc.date.issued 1992-02 -
dc.description.abstract Nonequilibrium states of surface composition can be extremely long-lived when polymer chains adsorb competitively. In a model system (polymethylmethacrylate adsorbed from CCl4 onto oxidized silicon previously saturated with polystyrene), it is shown that a weakly adsorbing polymer was sterically pinned to a surface by a more strongly adsorbing polymer. The dynamical evolution of the surface composition was strongly nonexponential in time and non-Arrhenius in temperature; the phenomenology is analogous to bulk glasses. This interpretation offers a new mechanism to explain why weakly adsorbing chains may bind to surfaces, as well as a direction in which to look for a method to release them. -
dc.identifier.bibliographicCitation SCIENCE, v.255, no.5047, pp.966 - 968 -
dc.identifier.doi 10.1126/science.255.5047.966 -
dc.identifier.issn 0036-8075 -
dc.identifier.scopusid 2-s2.0-0026811360 -
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/47460 -
dc.identifier.url https://science.sciencemag.org/content/255/5047/966 -
dc.identifier.wosid A1992HE60500034 -
dc.language 영어 -
dc.publisher AMER ASSOC ADVANCEMENT SCIENCE -
dc.title NEW MECHANISM OF NONEQUILIBRIUM POLYMER ADSORPTION -
dc.type Article -
dc.description.isOpenAccess FALSE -
dc.relation.journalWebOfScienceCategory Multidisciplinary Sciences -
dc.relation.journalResearchArea Science & Technology - Other Topics -
dc.type.docType Article -
dc.description.journalRegisteredClass scie -
dc.description.journalRegisteredClass scopus -
dc.subject.keywordPlus SOLID-LIQUID INTERFACE -
dc.subject.keywordPlus KINETICS -
dc.subject.keywordPlus EXCHANGE -

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