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Kim, Kwang S.
Center for Superfunctional Materials (CSM)
Research Interests
  • Theoretical/experimental nanosciences, molecular electronics spectroscopy, energy materials

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Precise tuning of cationic cyclophanes toward highly selective fluorogenic recognition of specific biophosphate anions

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Title
Precise tuning of cationic cyclophanes toward highly selective fluorogenic recognition of specific biophosphate anions
Author
Yousuf, MuhammadAhmed, NisarShirinfar, BaharehMiriyala, Vijay MadhavYoun, Il SeungKim, Kwang S.
Keywords
PHYSIOLOGICAL PH; AQUEOUS-SOLUTION; FLUORESCENT SENSORS; PI INTERACTION; RECEPTORS; IMIDAZOLIUM; BINDING; ATP; GTP; CHEMOSENSOR
Issue Date
201404
Publisher
AMER CHEMICAL SOC
Citation
ORGANIC LETTERS, v.16, no.8, pp.2150 - 2153
Abstract
Cationic cyclophanes with bridging and spacer groups possess well-organized semirigid cavities and are able to encapsulate and stabilize anionic species through diverse molecular interactions. We highlight the precise tuning of functionalized cyclophanes toward selective recognition of AMP, GTP, and pyrophosphate (PPi) using fluorescence, NMR spectroscopy, and density functional theory (DFT).
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DOI
http://dx.doi.org/10.1021/ol500613y
ISSN
1523-7060
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