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양창덕

Yang, Changduk
Advanced Tech-Optoelectronic Materials Synthesis Lab.
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dc.citation.endPage 7359 -
dc.citation.number 35 -
dc.citation.startPage 7354 -
dc.citation.title TETRAHEDRON -
dc.citation.volume 69 -
dc.contributor.author Kim, Gyoungsik -
dc.contributor.author Lee, Kyu Cheol -
dc.contributor.author Kim, Jonggi -
dc.contributor.author Lee, Jeong Chul -
dc.contributor.author Lee, Sang Myeon -
dc.contributor.author Lee, Jeong Chu -
dc.contributor.author Seo, Jung Hwa -
dc.contributor.author Choi, Won-Youl -
dc.contributor.author Yang, Changduk -
dc.date.accessioned 2023-12-22T03:38:28Z -
dc.date.available 2023-12-22T03:38:28Z -
dc.date.created 2013-08-20 -
dc.date.issued 2013-09 -
dc.description.abstract Cycloaddition is one of the best-studied types of reactions in the organic chemistry of fullerenes, engendering [6,6]-closed adducts in the vast majority of cases. Notwithstanding that a formation of open fulleroid structures is undoubtedly of theoretical interest, no one has demonstrated the conformation of [5,6]-open fulleroid via the direct cycloadditions. Here, we establish that cycloaddition between C60 and benzyne in situ generated from 2-amino-4,5-dibutoxybenzoic acid affords a new type of elusive [5,6]-open structure that is characterized on the basis of NMR, UV-vis spectroscopy, and cyclic voltammetry. Additionally, from density functional theory (DFT) calculations for possible [5,6]-open and [6,6]-closed adducts induced of benzyne-C60 reaction, as expected, features such as the charge distributions, binding characteristics, and frontier molecular orbital levels, are affected by the different binding modes in C60 cage. -
dc.identifier.bibliographicCitation TETRAHEDRON, v.69, no.35, pp.7354 - 7359 -
dc.identifier.doi 10.1016/j.tet.2013.06.073 -
dc.identifier.issn 0040-4020 -
dc.identifier.scopusid 2-s2.0-84880719257 -
dc.identifier.uri https://scholarworks.unist.ac.kr/handle/201301/4019 -
dc.identifier.url http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84880719257 -
dc.identifier.wosid 000322557500021 -
dc.language 영어 -
dc.publisher PERGAMON-ELSEVIER SCIENCE LTD -
dc.title An unprecedented [5,6]-open adduct via a direct benzyne-C-60 cycloaddition -
dc.type Article -
dc.relation.journalWebOfScienceCategory Chemistry, Organic -
dc.relation.journalResearchArea Chemistry -
dc.description.journalRegisteredClass scie -
dc.description.journalRegisteredClass scopus -
dc.subject.keywordAuthor [5,6]-Open adduct -
dc.subject.keywordAuthor [6,6]-Closed adduct -
dc.subject.keywordAuthor Benzyne -
dc.subject.keywordAuthor Buckminsterfullerene -
dc.subject.keywordAuthor Cycloaddition -

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