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DC Field | Value | Language |
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dc.citation.endPage | 7359 | - |
dc.citation.number | 35 | - |
dc.citation.startPage | 7354 | - |
dc.citation.title | TETRAHEDRON | - |
dc.citation.volume | 69 | - |
dc.contributor.author | Kim, Gyoungsik | - |
dc.contributor.author | Lee, Kyu Cheol | - |
dc.contributor.author | Kim, Jonggi | - |
dc.contributor.author | Lee, Jeong Chul | - |
dc.contributor.author | Lee, Sang Myeon | - |
dc.contributor.author | Lee, Jeong Chu | - |
dc.contributor.author | Seo, Jung Hwa | - |
dc.contributor.author | Choi, Won-Youl | - |
dc.contributor.author | Yang, Changduk | - |
dc.date.accessioned | 2023-12-22T03:38:28Z | - |
dc.date.available | 2023-12-22T03:38:28Z | - |
dc.date.created | 2013-08-20 | - |
dc.date.issued | 2013-09 | - |
dc.description.abstract | Cycloaddition is one of the best-studied types of reactions in the organic chemistry of fullerenes, engendering [6,6]-closed adducts in the vast majority of cases. Notwithstanding that a formation of open fulleroid structures is undoubtedly of theoretical interest, no one has demonstrated the conformation of [5,6]-open fulleroid via the direct cycloadditions. Here, we establish that cycloaddition between C60 and benzyne in situ generated from 2-amino-4,5-dibutoxybenzoic acid affords a new type of elusive [5,6]-open structure that is characterized on the basis of NMR, UV-vis spectroscopy, and cyclic voltammetry. Additionally, from density functional theory (DFT) calculations for possible [5,6]-open and [6,6]-closed adducts induced of benzyne-C60 reaction, as expected, features such as the charge distributions, binding characteristics, and frontier molecular orbital levels, are affected by the different binding modes in C60 cage. | - |
dc.identifier.bibliographicCitation | TETRAHEDRON, v.69, no.35, pp.7354 - 7359 | - |
dc.identifier.doi | 10.1016/j.tet.2013.06.073 | - |
dc.identifier.issn | 0040-4020 | - |
dc.identifier.scopusid | 2-s2.0-84880719257 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/4019 | - |
dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84880719257 | - |
dc.identifier.wosid | 000322557500021 | - |
dc.language | 영어 | - |
dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | - |
dc.title | An unprecedented [5,6]-open adduct via a direct benzyne-C-60 cycloaddition | - |
dc.type | Article | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | [5,6]-Open adduct | - |
dc.subject.keywordAuthor | [6,6]-Closed adduct | - |
dc.subject.keywordAuthor | Benzyne | - |
dc.subject.keywordAuthor | Buckminsterfullerene | - |
dc.subject.keywordAuthor | Cycloaddition | - |
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