dc.citation.conferencePlace |
KO |
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dc.citation.conferencePlace |
대전, 대전컨벤션센터 (DCC) |
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dc.citation.title |
2016 Fall Korean Institute of Chemical Engineers Meeting |
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dc.contributor.author |
Sa, Young Jin |
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dc.contributor.author |
Woo, Jinwoo |
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dc.contributor.author |
Kim, Min Gyu |
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dc.contributor.author |
Kim, Tae-Young |
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dc.contributor.author |
Joo, Sang Hoon |
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dc.date.accessioned |
2023-12-19T20:06:30Z |
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dc.date.available |
2023-12-19T20:06:30Z |
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dc.date.created |
2017-01-08 |
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dc.date.issued |
2016-10-20 |
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dc.description.abstract |
Iron-nitrogen on carbon (Fe-N/C) catalysts with Fe-Nx active sites have emerged as promising non-precious metal catalysts (NPMCs) for oxygen reduction reaction (ORR) in energy conversion and storage devices. However, rational design of Fe-N/C catalysts with abundant Fe-Nx species represents a challenge. In this talk, a general “silicaprotective-layer-assisted” approach that enables the preferential generation of active Fe-Nx sites while suppressing the formation of less active large Fe-based particles is presented. The resulting catalyst comprised of carbon nanotube wrapped with thin porphyrinic carbon layer (CNT/PC) showed high ORR activity and remarkable stability in alkaline media. Importantly, a CNT/PC-based cathode exhibited record high current and power densities in an alkaline anion exchange membrane fuel cell (AEMFC) among NPMC-based AEMFCs, and also showed excellent performances in acidic proton exchange membrane fuel cells. We further demonstrated the generality of this synthetic strategy to other carbon supports including reduced graphene oxides and carbon blacks. |
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dc.identifier.bibliographicCitation |
2016 Fall Korean Institute of Chemical Engineers Meeting |
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dc.identifier.uri |
https://scholarworks.unist.ac.kr/handle/201301/40175 |
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dc.identifier.url |
https://www.cheric.org/proceeding_disk/kiche2016f/2355.pdf |
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dc.language |
영어 |
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dc.publisher |
한국화학공학회 |
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dc.title |
Generalized Route to Fe-N/C Electrocatalysts with Preferentially Generated Fe-Nx Active Sites for Efficient Oxygen Reduction Reaction |
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dc.type |
Conference Paper |
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dc.date.conferenceDate |
2016-10-19 |
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