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Catalytic Conversion of Undaria Pinnatifida Over Nanoporous Materials Using Py-GC/MS

Author(s)
Park, Young-KwonJun, Bo RamJoo, Sang HoonSa, Young JinPark, Sung HoonJeon, Jong-KiJeong, Kwang-Eun
Issued Date
2013-12
DOI
10.1166/jnn.2013.8125
URI
https://scholarworks.unist.ac.kr/handle/201301/3985
Fulltext
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84892741674
Citation
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, v.13, no.12, pp.7794 - 7800
Abstract
Catalytic pyrolysis of Undaria Pinnatifida was carried out over a nanoporous Al-SBA-15 catalyst for the first time. Pt nanoparticles were added to Al-SBA-15 to generate a Pt/Al-SBA-15 catalyst. The effect of the addition of the Pt nanoparticles on the catalytic pyrolysis was investigated. For rapid product analysis and catalyst evaluation, a pyrolysis-gas chromatography/mass spectrometry was used. The characteristics of the catalysts were analyzed using X-ray diffraction, nitrogen adsorption-desorption, transmission electron microscope, NH3 temperature programmed desorption, and inductively coupled plasma optical emission spectrometer. Compared to the non-catalytic pyrolysis, catalytic pyrolysis over Al-SBA-15 produced a higher-quality bio-oil with a high stability and a low oxygen content. When Pt/Al-SBA-15 was used, compared to Al-SBA-15, the improvement of bio-oil quality was more profound; the yield of high-value-added aromatics increased, while the yields of acids and oxygenates decreased.
Publisher
AMER SCIENTIFIC PUBLISHERS
ISSN
1533-4880

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