There are no files associated with this item.
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 10876 | - |
dc.citation.number | 19 | - |
dc.citation.startPage | 10869 | - |
dc.citation.title | INORGANIC CHEMISTRY | - |
dc.citation.volume | 52 | - |
dc.contributor.author | Song, Xiaokai | - |
dc.contributor.author | Oh, Minhak | - |
dc.contributor.author | Lah, Myoung Soo | - |
dc.date.accessioned | 2023-12-22T03:36:50Z | - |
dc.date.available | 2023-12-22T03:36:50Z | - |
dc.date.created | 2013-10-18 | - |
dc.date.issued | 2013-10 | - |
dc.description.abstract | A series of isostructural hybrid bimetallic metal-organic frameworks (MOFs), NixM1-x-ITHDs [M = Zn(II), Co(II)], have been prepared via a conventional solvothermal reaction in the presence of varying mole ratios of Ni(II)/Zn(II) or Ni(II)/Co(II) mixed metal ions. While a critical amount of the doped Ni(II) ion (more than ≈0.2 mol fraction) is needed to have any enhancement of the framework stability of the hybrid bimetallic Ni xZn1-x-ITHDs, even a very small amount of the doped Ni(II) ion (≈0.1 mol fraction) produced a full enhancement of the framework stability of the hybrid bimetallic NixCo1-x-ITHDs. The highly porous and rigid NixCo1-x-ITHDs activated via a conventional vacuum drying process shows a Brunauer-Emmett-Teller specific surface area of 5370 m2 g-1, which is comparable to that of pure Ni-ITHD. The CO2 uptake capacities of Ni-ITHD and Ni 0.11Co0.89-ITHD (2.79 and 2.71 g g-1, respectively) at 1 bar and 195 K are larger than those of any other reported MOFs under similar conditions and the excess CO2 uptake capacity at 40 bar and 295 K (≈1.50 g g-1) is comparable to those of other MOFs, which are activated via the supercritical carbon dioxide drying process, with similar pore volumes. | - |
dc.identifier.bibliographicCitation | INORGANIC CHEMISTRY, v.52, no.19, pp.10869 - 10876 | - |
dc.identifier.doi | 10.1021/ic400844v | - |
dc.identifier.issn | 0020-1669 | - |
dc.identifier.scopusid | 2-s2.0-84885095499 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/3906 | - |
dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84885095499 | - |
dc.identifier.wosid | 000326319800027 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Hybrid bimetallic metal-organic frameworks: Modulation of the framework stability and ultralarge CO2 uptake capacity | - |
dc.type | Article | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Tel : 052-217-1404 / Email : scholarworks@unist.ac.kr
Copyright (c) 2023 by UNIST LIBRARY. All rights reserved.
ScholarWorks@UNIST was established as an OAK Project for the National Library of Korea.