There are no files associated with this item.
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 3850 | - |
dc.citation.number | 10 | - |
dc.citation.startPage | 3843 | - |
dc.citation.title | ANALYTICAL CHEMISTRY | - |
dc.citation.volume | 81 | - |
dc.contributor.author | Park, Jin-Young | - |
dc.contributor.author | Lee, Yoon-Suk | - |
dc.contributor.author | Chang, Byoung-Yong | - |
dc.contributor.author | Karthikeyan, S. | - |
dc.contributor.author | Kim, Kwang S. | - |
dc.contributor.author | Kim, Byeang Hyean | - |
dc.contributor.author | Park, Su-Moon | - |
dc.date.accessioned | 2023-12-22T08:07:02Z | - |
dc.date.available | 2023-12-22T08:07:02Z | - |
dc.date.created | 2013-07-18 | - |
dc.date.issued | 2009-05 | - |
dc.description.abstract | A highly selective receptor for serotonin was designed using cages formed by the (R)-lipo-diaza-18-crown-6 self-assembled monolayer (SAM) on gold and experimentally verified by a variety of electrochemical experiments in solutions containing large amounts of dopamine and ascorbic acid, as well as other interferents. The molecular modeling study showed that parameters such as the H-pi interaction provided important driving forces for the cage to form a strong inclusion complex with serotonin. The charge-transfer resistance (R(CT)'s) to/from redox probe ions, Fe(CN)(6)(3-5-), was greatly enhanced because of their electrostatic attractions to ammonium ions of serotonin molecules captured by cages. The changes in R(CT)-values were shown to be remarkably selective for serotonin in the presence of many interferents. | - |
dc.identifier.bibliographicCitation | ANALYTICAL CHEMISTRY, v.81, no.10, pp.3843 - 3850 | - |
dc.identifier.doi | 10.1021/ac900220n | - |
dc.identifier.issn | 0003-2700 | - |
dc.identifier.scopusid | 2-s2.0-66149121454 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/3852 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/ac900220n | - |
dc.identifier.wosid | 000266095100019 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | (R)-Lipo-Diaza-18-Crown-6 Self-Assembled Monolayer as a Selective Serotonin Receptor | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Analytical | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY | - |
dc.subject.keywordPlus | SCAN CYCLIC VOLTAMMETRY | - |
dc.subject.keywordPlus | LABEL-FREE DETECTION | - |
dc.subject.keywordPlus | FOURIER-TRANSFORM | - |
dc.subject.keywordPlus | ELECTRON-TRANSFER | - |
dc.subject.keywordPlus | RAT-BRAIN | - |
dc.subject.keywordPlus | THIOLATED CYCLODEXTRIN | - |
dc.subject.keywordPlus | FLUORESCENCE DETECTION | - |
dc.subject.keywordPlus | LIQUID-CHROMATOGRAPHY | - |
dc.subject.keywordPlus | NUCLEUS-ACCUMBENS | - |
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Tel : 052-217-1404 / Email : scholarworks@unist.ac.kr
Copyright (c) 2023 by UNIST LIBRARY. All rights reserved.
ScholarWorks@UNIST was established as an OAK Project for the National Library of Korea.