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- Lah, Myoung Soo
- Frontier Energy Storage Material Lab.
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Manganese(III)-Promoted Tandem Oxidation and Cyclization of beta-Keto Ester Derivatives of Terpenoids
- Author(s)
- Li, Zhilong, Jung, Heejung, Park, Mira, Lah, Myoung Soo, Koo, Sangho
- Issued Date
- 2011-08
- Citation
- ADVANCED SYNTHESIS & CATALYSIS, v.353, no.11-12, pp.1913 - 1917
- Abstract
- A new type of terpenoid cyclization directed by a beta-keto ester moiety has been developed, which proceeded by manganese(III)-initiated oxidation of the beta-keto ester, followed by an intramolecular hetero Diels-Alder reaction with the terpenoid chain. This reaction produces polycyclic dihydropyrans in high yields and stereoselectivities under mild conditions.
- Publisher
- WILEY-BLACKWELL
- ISSN
- 1615-4150
- Keyword (Author)
- cyclization, cycloaddition, manganese, oxidation, radical reactions, terpenoids
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