Manganese(III)-Promoted Tandem Oxidation and Cyclization of beta-Keto Ester Derivatives of Terpenoids
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- Manganese(III)-Promoted Tandem Oxidation and Cyclization of beta-Keto Ester Derivatives of Terpenoids
- Li, Zhilong; Jung, Heejung; Park, Mira; Lah, Myoung Soo; Koo, Sangho
- cyclization; cycloaddition; manganese; oxidation; radical reactions; terpenoids
- Issue Date
- ADVANCED SYNTHESIS & CATALYSIS, v.353, no.11-12, pp.1913 - 1917
- A new type of terpenoid cyclization directed by a beta-keto ester moiety has been developed, which proceeded by manganese(III)-initiated oxidation of the beta-keto ester, followed by an intramolecular hetero Diels-Alder reaction with the terpenoid chain. This reaction produces polycyclic dihydropyrans in high yields and stereoselectivities under mild conditions.
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