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BielawskiChristopher W

Bielawski, Christopher W.
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Ammonia N-H activation by a N,N '-diamidocarbene

Author(s)
Hudnall, Todd W.Moerdyk, Jonathan P.Bielawski, Christopher W.
Issued Date
2010
DOI
10.1039/c0cc00638f
URI
https://scholarworks.unist.ac.kr/handle/201301/33264
Fulltext
https://pubs.rsc.org/en/content/articlelanding/2010/CC/c0cc00638f#!divAbstract
Citation
CHEMICAL COMMUNICATIONS, v.46, no.24, pp.4288 - 4290
Abstract
The synthesis and characterization of N,N'-dimesityl-4,6-diketo-5,5-dimethylpyrimidin-2-ylidene is reported; this crystalline N,N'-diamidocarbene was found to split ammonia and engage in other reactions not exhibited by typical N-heterocyclic carbenes.
Publisher
ROYAL SOC CHEMISTRY
ISSN
1359-7345
Keyword
HETEROCYCLIC CARBENESDIHYDROGEN COMPLEXESOXIDATIVE ADDITIONHYDROGENCLEAVAGELIGANDSWATERBULKYBOND

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