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Baik, Jeong Min
Nano Energy and Environmental Materials Lab
Research Interests
  • Nanogenerators, antimicrobial material, catalysis, smart sensors

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Highly Single Crystalline IrxRu1-xO2 Mixed Metal Oxide Nanowires

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Title
Highly Single Crystalline IrxRu1-xO2 Mixed Metal Oxide Nanowires
Author
Lee, YuminShin, Hae-YoungChun, Sung HeeLee, JaeyeonPark, Won JeongBaik, Jeong MinYoon, SeokhyunKim, Myung Hwa
Keywords
Blue-shifted; Electrode material; Electrolysis of waters; Facile synthesis; Mixed metal oxide; Nano-structured; Relative ratios; Single-crystalline; Structural characterization; Vapor phase transport process
Issue Date
201208
Publisher
AMER CHEMICAL SOC
Citation
JOURNAL OF PHYSICAL CHEMISTRY C, v.116, no.30, pp.16300 - 16304
Abstract
The nanostructured iridium-ruthenium mixed metal oxide (IrxRu1-xO2, 0 <= x <= 1) is the most promising candidate as a highly efficient electrode material for the electrolysis of water. We present a facile synthesis and structural characterization of highly single crystalline IrxRu1-xO2 mixed metal oxide nanowires for the first time via a simple vapor phase transport process by carefully controlling the relative ratios of IrO2 and RuO2 precursors. We also observed that an E-g mode of an IrxRu1-xO2 nanowire measured from Raman scattering is being linearly blue shifted and its line width is asymmetrically broadened with respect to the increase of the Ir contents, indicating that we could quantitatively determine stoichiometry information as well as crystal structure for mixed metal oxide nanowires.
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DOI
http://dx.doi.org/10.1021/jp3048532
ISSN
1932-7447
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