There are no files associated with this item.
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 3726 | - |
dc.citation.number | 13 | - |
dc.citation.startPage | 3721 | - |
dc.citation.title | POLYMER | - |
dc.citation.volume | 44 | - |
dc.contributor.author | Bielawski, CW | - |
dc.contributor.author | Jethmalani, JM | - |
dc.contributor.author | Grubbs, RH | - |
dc.date.accessioned | 2023-12-22T11:11:10Z | - |
dc.date.available | 2023-12-22T11:11:10Z | - |
dc.date.created | 2020-07-13 | - |
dc.date.issued | 2003-06 | - |
dc.description.abstract | A convenient, one-pot synthesis of telechelic and semi-telechelic polyacrylates with unsaturated end-groups has been developed. Atom transfer radical polymerization of methyl or n-butyl acrylate was initiated with either ethyl alpha-bromomethylacrylate or methyl dichloroacetate, as a monofunctional or difunctional initiator, respectively, and mediated with various Cu/amine complexes. Addition of excess ethyl 2-bromomethylacrylate was found to not only immediately quench the polymerization but also installed 2-carbethoxyallyl moieties on the ends of the polymer chains. The telechelic polymers were found to undergo thermally or photochemically induced crosslinking reactions. | - |
dc.identifier.bibliographicCitation | POLYMER, v.44, no.13, pp.3721 - 3726 | - |
dc.identifier.doi | 10.1016/S0032-3861(03)00178-2 | - |
dc.identifier.issn | 0032-3861 | - |
dc.identifier.scopusid | 2-s2.0-0038361249 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/33062 | - |
dc.identifier.url | https://www.sciencedirect.com/science/article/pii/S0032386103001782?via%3Dihub | - |
dc.identifier.wosid | 000183436200013 | - |
dc.language | 영어 | - |
dc.publisher | ELSEVIER SCI LTD | - |
dc.title | Synthesis of telechelic polyacrylates with unsaturated end-groups | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Polymer Science | - |
dc.relation.journalResearchArea | Polymer Science | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | atom transfer radical polymerization | - |
dc.subject.keywordAuthor | telechelic polymers | - |
dc.subject.keywordAuthor | macromonomers | - |
dc.subject.keywordPlus | TRANSFER RADICAL POLYMERIZATION | - |
dc.subject.keywordPlus | POLYMERS | - |
dc.subject.keywordPlus | COMPLEX | - |
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Tel : 052-217-1404 / Email : scholarworks@unist.ac.kr
Copyright (c) 2023 by UNIST LIBRARY. All rights reserved.
ScholarWorks@UNIST was established as an OAK Project for the National Library of Korea.