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BielawskiChristopher W

Bielawski, Christopher W.
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An alternative synthesis of benzobis(imidazolium) salts via a 'one-pot' cyclization/oxidation reaction sequence

Author(s)
Boydston, Andrew J.Khramov, Dimitri M.Bielawski, Christopher W.
Issued Date
2006-07
DOI
10.1016/j.tetlet.2006.05.076
URI
https://scholarworks.unist.ac.kr/handle/201301/33055
Fulltext
https://www.sciencedirect.com/science/article/pii/S0040403906010008?via%3Dihub
Citation
TETRAHEDRON LETTERS, v.47, no.29, pp.5123 - 5125
Abstract
Cyclization of N-aryl and N-alkyl 2,5-diamino-1,4-benzoquinonediimines using paraformaldehyde under acidic conditions followed by oxidation with catalytic amounts of Pd(OAc)(2) afforded their respective benzobis(imidazolium) salts in yields of 48-98%. A comparative solid-state study between a 2,5-diamino-1,4-benzoquinonediimine and its corresponding benzobis(imidazolium) dichloride was also performed.
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
ISSN
0040-4039
Keyword
CARBENECOMPLEXESDERIVATIVESAZOPHENINEPOLYMERSQUINONE

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