There are no files associated with this item.
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 1054 | - |
dc.citation.number | 7 | - |
dc.citation.startPage | 1047 | - |
dc.citation.title | CHEMISTRY OF MATERIALS | - |
dc.citation.volume | 25 | - |
dc.contributor.author | Jeong, Seok | - |
dc.contributor.author | Kim, Dongwook | - |
dc.contributor.author | Song, Xiaokai | - |
dc.contributor.author | Choi, Min | - |
dc.contributor.author | Park, Noejung | - |
dc.contributor.author | Lah, Myoung Soo | - |
dc.date.accessioned | 2023-12-22T04:08:54Z | - |
dc.date.available | 2023-12-22T04:08:54Z | - |
dc.date.created | 2013-07-04 | - |
dc.date.issued | 2013-04 | - |
dc.description.abstract | Metal-organic frameworks, [Ni(HBTC) (dabco)] (2) and [Ni-2(HBTC)(2)(bipy)(0.6)(dabco)(1.4)] (3) (where H3BTC is 1,3,5-benzenetricarboxylic acid, dabco is 1,4-diazabicyclo[2.2.2]octane, and bipy is 4,4'-bipyridine), were prepared via postsynthetic ligand exchanges of [Ni(HBTC)(bipy)] (1). By controlling the concentration of dabco, we could obtain not only entropically favorable 2 with completely exchanged dabco but also enthalpically favorable 3 with selectively exchanged bipy/dabco in the alternating layers. | - |
dc.identifier.bibliographicCitation | CHEMISTRY OF MATERIALS, v.25, no.7, pp.1047 - 1054 | - |
dc.identifier.doi | 10.1021/cm303624p | - |
dc.identifier.issn | 0897-4756 | - |
dc.identifier.scopusid | 2-s2.0-84875970567 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/3279 | - |
dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84875970567 | - |
dc.identifier.wosid | 000317438600005 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Postsynthetic Exchanges of the Pillaring Ligand in Three-Dimensional Metal-Organic Frameworks | - |
dc.type | Article | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical; Materials Science, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry; Materials Science | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | metal-organic frameworks (MOFs) | - |
dc.subject.keywordAuthor | postsynthetic modification (PSM) | - |
dc.subject.keywordAuthor | postsynthetic ligand exchange (PSLE) | - |
dc.subject.keywordAuthor | enthalpically favorable exchange | - |
dc.subject.keywordAuthor | entropically favorable exchange | - |
dc.subject.keywordAuthor | gas sorption | - |
dc.subject.keywordAuthor | adsorption enthalpy | - |
dc.subject.keywordPlus | TOTAL-ENERGY CALCULATIONS | - |
dc.subject.keywordPlus | WAVE BASIS-SET | - |
dc.subject.keywordPlus | HYDROGEN STORAGE | - |
dc.subject.keywordPlus | ION-EXCHANGE | - |
dc.subject.keywordPlus | FUNCTIONALIZATION | - |
dc.subject.keywordPlus | CONSTRUCTION | - |
dc.subject.keywordPlus | SORPTION | - |
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Tel : 052-217-1404 / Email : scholarworks@unist.ac.kr
Copyright (c) 2023 by UNIST LIBRARY. All rights reserved.
ScholarWorks@UNIST was established as an OAK Project for the National Library of Korea.