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DC Field | Value | Language |
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dc.citation.startPage | 166881 | - |
dc.citation.title | JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS | - |
dc.citation.volume | 508 | - |
dc.contributor.author | Islah-u-din | - |
dc.contributor.author | Chong, Shen, V | - |
dc.contributor.author | Jameson, Geoffrey B. | - |
dc.contributor.author | Raymond, Sebastiampillai G. | - |
dc.contributor.author | Lee, Geunsik | - |
dc.contributor.author | Park, In K. | - |
dc.contributor.author | Wang, Xiaolin | - |
dc.contributor.author | Waterland, Mark R. | - |
dc.contributor.author | Tallon, Jeffery L. | - |
dc.date.accessioned | 2023-12-21T17:11:46Z | - |
dc.date.available | 2023-12-21T17:11:46Z | - |
dc.date.created | 2020-05-14 | - |
dc.date.issued | 2020-08 | - |
dc.description.abstract | A three-dimensional (3D) framework of covalently-bonded layers of bimetallic inorganic oxide, CuMoO4, interlinked by electron-rich organic ligands, which is semiconducting and also ferromagnetic, has been prepared. The structure [Cu(3,8-phenanthroline)(0.5)MoO4] consists of molybdate tetrahedra corner-shared with clusters of edge-sharing {CuO5N} octahedra. The injection of charge carriers into the inorganic layers by phenanthroline induces different magnetic orderings at different temperatures, orderings which are not found in the structurallysimilar [Cu(4,4'-bipyridine)(0.5)MoO4]. The temperature dependence of the susceptibility shows two low temperature magnetic transitions: weakly ferromagnetic-coupled spins below 15 K coexisting with an anti-ferromagnetic structure below 10 K. Specific heat capacity shows a finite ground-state electronic specific heat coefficient, gamma = 0.094 J/mol.K-2, that is higher than that of the bipyridine counterpart (0.068 J/mol.K-2), confirming an increase in the electronic density-of-states in the phenanthroline system. | - |
dc.identifier.bibliographicCitation | JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, v.508, pp.166881 | - |
dc.identifier.doi | 10.1016/j.jmmm.2020.166881 | - |
dc.identifier.issn | 0304-8853 | - |
dc.identifier.scopusid | 2-s2.0-85083035183 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/32051 | - |
dc.identifier.url | https://www.sciencedirect.com/science/article/pii/S0304885319341824 | - |
dc.identifier.wosid | 000535903300006 | - |
dc.language | 영어 | - |
dc.publisher | ELSEVIER | - |
dc.title | A new class of ferromagnetic semiconductor: Copper molybdate organic-inorganic compound with phenanthroline organic linkers | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary; Physics, Condensed Matter | - |
dc.relation.journalResearchArea | Materials Science; Physics | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | Magnetic properties | - |
dc.subject.keywordAuthor | Layered compounds | - |
dc.subject.keywordAuthor | Organic-inorganic hybrids | - |
dc.subject.keywordAuthor | Doping | - |
dc.subject.keywordAuthor | Polycyclic aromatic hydrocarbons | - |
dc.subject.keywordPlus | HYDROTHERMAL SYNTHESIS | - |
dc.subject.keywordPlus | FUNCTIONAL MATERIALS | - |
dc.subject.keywordPlus | ORGANOAMINE LIGANDS | - |
dc.subject.keywordPlus | MAGNETIC-PROPERTIES | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | CUMOO4 | - |
dc.subject.keywordPlus | TRANSITION | - |
dc.subject.keywordPlus | HYBRIDS | - |
dc.subject.keywordPlus | COMPLEXES | - |
dc.subject.keywordPlus | OXIDES | - |
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