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BielawskiChristopher W

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Improving efficiencies by modulating the central metal ion in porphyrin-oligothiophene-mediated P3HT/PCBM organic solar cells

Author(s)
Lyons, Dani M.Kesters, JurgenMaes, WouterBielawski, Christopher W.Sessler, Jonathan L.
Issued Date
2013-08
DOI
10.1016/j.synthmet.2013.06.013
URI
https://scholarworks.unist.ac.kr/handle/201301/31487
Fulltext
https://www.sciencedirect.com/science/article/pii/S0379677913002981?via%3Dihub
Citation
SYNTHETIC METALS, v.178, pp.56 - 61
Abstract
The power conversion efficiencies of poly(3-hexylthiophene)/[6,6]-phenyl-C-61-butyric acid methyl ester (P3HT/PCBM) bulk heterojunction organic solar cells were increased through the addition of small amounts (1-10%) of metalloporphyrin-oligothiophene conjugates. The effectiveness of these porphyrin additives was found to increase in the order free-base < Co < Zn < Ni < Cu, with the efficiency being enhanced by up to 17% for the terthiophene-substituted Cu(II)-porphyrin, pointing to an important effect of the metal center.
Publisher
ELSEVIER SCIENCE SA
ISSN
0379-6779
Keyword (Author)
PorphyrinsOrganic photovoltaicsBulk heterojunctionsTernary blends
Keyword
POLYMER PHOTOVOLTAIC CELLSPERFORMANCEADDITIVESFULLERENEBLENDSSTRENGTH

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