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Author

Lah, Myoung Soo
Nanoporous Materials Lab
Research Interests
  • Metal-Organic Frameworks (MOFs)

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A Microporous Metal-Organic Framework Based on [2+2] Parallel and Inclined Interpenetrated 2D Sheets Interconnected by an Auxiliary Linker

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Title
A Microporous Metal-Organic Framework Based on [2+2] Parallel and Inclined Interpenetrated 2D Sheets Interconnected by an Auxiliary Linker
Author
Song, XiaokaiLiu, XinfangOh, MinhakLah, Myoung Soo
Keywords
3D networks; Bridging diamines; Dicarboxylic acid; Helical channels; Metal organic framework; Micro-porous; Rotational flexibility; Secondary building units
Issue Date
201007
Publisher
AMER CHEMICAL SOC
Citation
CRYSTAL GROWTH & DESIGN, v.10, no.7, pp.3222 - 3227
Abstract
A microporous metal organic framework (MOE), [Zn2L2(dabco)], was prepared using a long and rigid dicarboxylic acid, 1,4-bis(3-carboxylphenylethynyl)benzene (H2L), with some rotational flexibility, and an auxiliary bridging diamine linker, 1,4-diazabicyclo[2.2.2]octane (dabco). The MOE, based on a Zn paddle-wheel secondary building unit, has [2 + 2] parallel and inclined interpenetrating 2D sheets interconnected by dabco to form a 3D network with 1D helical channels.
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DOI
http://dx.doi.org/10.1021/cg100357q
ISSN
1528-7483
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