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DC Field | Value | Language |
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dc.citation.endPage | 4193 | - |
dc.citation.number | 8 | - |
dc.citation.startPage | 4186 | - |
dc.citation.title | CRYSTAL GROWTH & DESIGN | - |
dc.citation.volume | 12 | - |
dc.contributor.author | Lah, Myoung Soo | - |
dc.contributor.author | Kim, Dongwook | - |
dc.contributor.author | Song, Xiaokai | - |
dc.contributor.author | Yoon, Jung Hee | - |
dc.date.accessioned | 2023-12-22T04:49:04Z | - |
dc.date.available | 2023-12-22T04:49:04Z | - |
dc.date.created | 2013-05-29 | - |
dc.date.issued | 2012-08 | - |
dc.description.abstract | The solvothermal reactions of cobalt(II) chloride hexahydrate and 1,3,5-benzenetribenzoic acid (H3BTB) in anhydrous N,N'-dimethylacetamide (DMA) at two different reaction temperatures and reactant concentrations led to two 3,6-connected metal-organic frameworks (MOFs) with different net topologies based on the ligand as a C-3 symmetric 3-connected organic node and the linear trinuclear cobalt carboxylate cluster, Co-3(COO)(6), as a 6-connected secondary building unit (SBU). MOF [Co-3(BTB)(2)(DMA)(4)], 1, with a linear trinuclear cobalt carboxylate cluster, Co-3(COO)(6), and with an inversion point symmetry with "compressed trigonal antiprismatic" 6-connectivity, is a two-dimensional (2-D) layered structure of a 3,6-connected kgd net topology. However, the same linear trinuclear cobalt carboxylate cluster, Co-3(COO)(6), with a 2-fold point symmetry with "compressed trigonal prismatic" 6-connectivity leads to the three-dimensional (3-D) network of 2, with an unprecedented 3,6-connected net topology with the point symbol (4(3))(2)(4(3).12(12)). The 2-D layered framework, 1, shows a significant sorption hysteresis for adsorbates with relatively strong interactions with the framework, such as N-2 and CO2. | - |
dc.identifier.bibliographicCitation | CRYSTAL GROWTH & DESIGN, v.12, no.8, pp.4186 - 4193 | - |
dc.identifier.doi | 10.1021/cg300686n | - |
dc.identifier.issn | 1528-7483 | - |
dc.identifier.scopusid | 2-s2.0-84864755974 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/2876 | - |
dc.identifier.url | http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84864755974 | - |
dc.identifier.wosid | 000306942300047 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | 3,6-Connected Metal-Organic Frameworks Based on Triscarboxylate as a 3-Connected Organic Node and a Linear Trinuclear Co-3(COO)(6) Secondary Building Unit as a 6-Connected Node | - |
dc.type | Article | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary; Crystallography; Materials Science, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry; Crystallography; Materials Science | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
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