Edge-Functionalization of Pyrene as a Miniature Graphene via Friedel-Crafts Acylation Reaction in Poly(Phosphoric Acid)
Cited 5 times inCited 4 times in
- Edge-Functionalization of Pyrene as a Miniature Graphene via Friedel-Crafts Acylation Reaction in Poly(Phosphoric Acid)
- Jeon, In-Yup; Choi, Eun-Kyoung; Bae, Seo-Yoon; Baek, Jong-Beom
- Benzamides; Characterization techniques; Friedel-crafts acylation; Functionalizations; Functionalized; Graphenes; Model reactions; Model study; N-methyl-2-pyrrolidone; Phosphorous pentoxide; Poly (phosphoric acid); Reaction conditions
- Issue Date
- NANOSCALE RESEARCH LETTERS, v.5, no.10, pp.1686 - 1691
- The feasibility of edge-functionalization of graphite was tested via the model reaction between pyrene and 4-(2,4,6-trimethylphenyloxy)benzamide (TMPBA) in poly(phosphoric acid) (PPA)/phosphorous pentoxide (P(2)O(5)) medium. The functionalization was confirmed by various characterization techniques. On the basis of the model study, the reaction condition could be extended to the edge-functionalization of graphite with TMPBA. Preliminary results showed that the resultant TMPBA-grafted graphite (graphite-g-TMPBA) was found to be readily dispersible in N-methyl-2-pyrrolidone (NMP) and can be used as a precursor for edge-functionalized graphene (EFG).
- ; Go to Link
Appears in Collections:
- ECHE_Journal Papers
- Files in This Item:
can give you direct access to the published full text of this article. (UNISTARs only)
Show full item record
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.