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DC Field | Value | Language |
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dc.citation.startPage | 111046 | - |
dc.citation.title | JOURNAL OF MOLECULAR LIQUIDS | - |
dc.citation.volume | 288 | - |
dc.contributor.author | Noh, Juran | - |
dc.contributor.author | Jung, Sunfwoo | - |
dc.contributor.author | Kim, Gyoungsik | - |
dc.contributor.author | Koo, Dong Geon | - |
dc.contributor.author | Choi, Kyoung Soon | - |
dc.contributor.author | Shin, Tae Joo | - |
dc.contributor.author | Yang, Changduk | - |
dc.contributor.author | Park, Juhyun | - |
dc.date.accessioned | 2023-12-21T18:53:19Z | - |
dc.date.available | 2023-12-21T18:53:19Z | - |
dc.date.created | 2019-06-17 | - |
dc.date.issued | 2019-08 | - |
dc.description.abstract | Nanoassemblies of an organic semiconductor based on thienoisoindigo were prepared by forming nanomorphologies in phase-separated films of a thienoisoindigo-based molecule (TIIG-Bz), bromobenzaldehydes (BBAs), and a phospholipid, 1,2-dioctanoyl-sn-glycero-3-phosphocholine (D8PC), and then shattering the films via penetration of water into polar domains. It was suggested that 2-BBA associated with TIIG-Bz via intermolecular halogen and chalcogen bonding between the electron-deficient δ-holes of bromine in 2-BBA and sulfur in TIIG-Bz, and their electron-rich counterparts, carbonyl oxygen, in TIIG-Bz and 2-BBA, filling empty space in the conjugated planes. This resulted in the π-π stacking of conjugated planes overwhelming the lateral packing of alkyl chains as the ratios of 2-BBA and the lipid to TIIG-Bz increased and decreased, respectively, as proven by bathochromic shifts in the absorption spectra and grazing incidence X-ray diffraction patterns. It was concluded that, by varying the 2-BBA and D8PC compositions, the water-dispersed nanomorphologies of the organic semiconductor can be controlled via the competition of hydrophobic interactions between alkyl chains for lateral association for zero-dimensional growth and intermolecular π-π interactions for one-dimensional growth. | - |
dc.identifier.bibliographicCitation | JOURNAL OF MOLECULAR LIQUIDS, v.288, pp.111046 | - |
dc.identifier.doi | 10.1016/j.molliq.2019.111046 | - |
dc.identifier.issn | 0167-7322 | - |
dc.identifier.scopusid | 2-s2.0-85066495227 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/27178 | - |
dc.identifier.url | https://www.sciencedirect.com/science/article/pii/S0167732219318458?via%3Dihub | - |
dc.identifier.wosid | 000480664700041 | - |
dc.language | 영어 | - |
dc.publisher | Elsevier B.V. | - |
dc.title | Aqueous dispersions of thienoisoindigo-based semiconductor nanorods assembled with 2-bromobenzaldehyde and a phospholipid | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical; Physics, Atomic, Molecular & Chemical | - |
dc.relation.journalResearchArea | Chemistry; Physics | - |
dc.type.docType | Article | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | Chalcogen bonding | - |
dc.subject.keywordAuthor | Halogen bonding | - |
dc.subject.keywordAuthor | Nanorod | - |
dc.subject.keywordAuthor | Phase-separated film shattering | - |
dc.subject.keywordAuthor | Phospholipid | - |
dc.subject.keywordAuthor | Thienoisoindigo | - |
dc.subject.keywordPlus | Association reactions | - |
dc.subject.keywordPlus | Hydrophobicity | - |
dc.subject.keywordPlus | Nanorods | - |
dc.subject.keywordPlus | Chalcogens | - |
dc.subject.keywordPlus | Grazing incidence X-ray diffraction | - |
dc.subject.keywordPlus | Halogen bonding | - |
dc.subject.keywordPlus | Hydrophobic interactions | - |
dc.subject.keywordPlus | One-dimensional growth | - |
dc.subject.keywordPlus | Phase-separated film shattering | - |
dc.subject.keywordPlus | Semiconductor nanorods | - |
dc.subject.keywordPlus | Thienoisoindigo | - |
dc.subject.keywordPlus | Phospholipids | - |
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