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Author

Cho, Jaephil
Nano Energy Storage Materials Lab (NESM)
Research Interests
  • Li-ion battery, metal-air battery, redox-flow battery, flexible battery .

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Nanoparticle-Nanorod Core-Shell LiNi0.5Mn1.5O4 Spinel Cathodes with High Energy Density for Li-Ion Batteries

Cited 32 times inthomson ciCited 33 times inthomson ci
Title
Nanoparticle-Nanorod Core-Shell LiNi0.5Mn1.5O4 Spinel Cathodes with High Energy Density for Li-Ion Batteries
Author
Jo, MinkiLee, Young-KiKim, Kwang ManCho, Jaephil
Keywords
Core-shell; Discharge capacities; Energy density; High energy densities; Li-ion batteries; Nanorod assembly; Sol-gel methods; Spinel cathodes
Issue Date
2010
Publisher
ELECTROCHEMICAL SOC INC
Citation
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, v.157, no.7, pp.A841 - A845
Abstract
Nanoparticle-nanorod core-shell LiNi0.5Mn1.5O4 spinel cathodes for Li-ion batteries were prepared using a hollow MnO2 precursor. The core and shell parts consisted of nanoparticle (similar to 100 nm) and nanorod assemblies, respectively. The core-shell cathode exhibited greatly improved discharge capacities compared to nanoparticles prepared by a sol-gel method. The core-shell spinel exhibited discharge capacities of 121 and 100 mAh/g at 0.1C and 7C rates, respectively, whereas a spinel cathode prepared by a sol-gel method exhibited 99 and 80 mAh/g at those respective rates. In addition, the core-shell spinels demonstrated an energy density value that was enhanced by 52% to 1.6 Wh/cm(3) compared to an analogous sample prepared by a sol-gel method, which showed a value of 0.9 Wh/cm(3).
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DOI
http://dx.doi.org/10.1149/1.3428706
ISSN
0013-4651
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ECHE_Journal Papers

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