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Composite cathodes composed of NdBa0.5Sr0.5Co 2O5+δ and Ce0.9Gd0.1O 1.95 for intermediate-temperature solid oxide fuel cells

Author(s)
Kim, JiyounSeo, Won-YongShin, JeeyoungLiu , MeilinKim, Guntae
Issued Date
2013-01
DOI
10.1039/c2ta00025c
URI
https://scholarworks.unist.ac.kr/handle/201301/2627
Fulltext
http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=84876582728
Citation
JOURNAL OF MATERIALS CHEMISTRY A, v.1, no.3, pp.515 - 519
Abstract
The electrochemical properties of a composite cathode composed of NdBa0.5Sr0.5Co2O5+delta (NBSCO) and Ce0.9Gd0.1O1.95 (GDC) are investigated for intermediate-temperature solid oxide fuel cells (IT-SOFCs). In particular, cells based on NBSCO-GDC composite cathodes demonstrated higher performance than those based on a NBSCO cathode, probably due to the extended triple phase boundary (TPB) length. The oxygen reduction mechanism on the NBSCO-GDC composite cathodes is proposed to explain the superior electrochemical behaviour.
Publisher
ROYAL SOC CHEMISTRY
ISSN
2050-7488
Keyword
ELECTROCHEMICAL PROPERTIESTHERMAL-EXPANSIONOXYGEN REDUCTIONDOPED CERIAPEROVSKITEELECTROLYTESSOFCSLNBACO(2)O(5+DELTA)ELECTRODESMECHANISM

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