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DC Field | Value | Language |
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dc.citation.endPage | 2512 | - |
dc.citation.number | 10 | - |
dc.citation.startPage | 2504 | - |
dc.citation.title | ACS ENERGY LETTERS | - |
dc.citation.volume | 3 | - |
dc.contributor.author | Moon, Chang Ki | - |
dc.contributor.author | Lee, Hyun-Jae | - |
dc.contributor.author | Park, Kern Ho | - |
dc.contributor.author | Kwak, Hiram | - |
dc.contributor.author | Heo, Jongwook W. | - |
dc.contributor.author | Choi, Keunsu | - |
dc.contributor.author | Yang, Hyemi | - |
dc.contributor.author | Kim, Maeng-Suk | - |
dc.contributor.author | Hong, Seung-Tae | - |
dc.contributor.author | Lee, Jun Hee | - |
dc.contributor.author | Jung, Yoon Seok | - |
dc.date.accessioned | 2023-12-21T20:08:56Z | - |
dc.date.available | 2023-12-21T20:08:56Z | - |
dc.date.created | 2018-11-06 | - |
dc.date.issued | 2018-10 | - |
dc.description.abstract | Mechanically sinterable sulfide Na+ superionic conductors are key to enabling room-temperature-operable all-solid-state Na-ion batteries (ASNBs) for large-scale energy storage applications. To date, few candidates can fulfill the requirement of a high ionic conductivity of >= 1 mS cm(-1) using abundant, cost-effective, and nontoxic elements. Herein, the development of a new Na+ superionic conductor, Ca-doped cubic Na3PS4, showing a maximum conductivity of similar to 1 mS cm(-1) at 25 degrees C is described. Complementary analyses using conductivity measurement by the AC impedance method, Na-23 nuclear magnetic resonance spectroscopy, and density functional theory calculations reveal that the aliovalent substitution of Na' in Na3PS4 with Ca2+ renders a cubic phase with Na vacancies, which increases the activation barriers but drastically enhances Na-ion diffusion. It is demonstrated that TiS2/Na-Sn ASNBs emp oying Ca-doped Na3PS4 exhibit a high charge capacity of 200 mA h g(-1) at 0.06C, good cycling performance, and higher rate capability than those employing undoped cubic Na3PS4 | - |
dc.identifier.bibliographicCitation | ACS ENERGY LETTERS, v.3, no.10, pp.2504 - 2512 | - |
dc.identifier.doi | 10.1021/acsenergylett.8b01479 | - |
dc.identifier.issn | 2380-8195 | - |
dc.identifier.scopusid | 2-s2.0-85053890850 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/25147 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/acsenergylett.8b01479 | - |
dc.identifier.wosid | 000447581500030 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Vacancy-Driven Na+ Superionic Conduction in New Ca-Doped Na3PS4 for All-Solid-State Na-Ion Batteries | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical; Electrochemistry; Energy & Fuels; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry; Electrochemistry; Energy & Fuels; Science & Technology - Other Topics; Materials Science | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | RECHARGEABLE BATTERIES | - |
dc.subject.keywordPlus | ELECTROLYTES | - |
dc.subject.keywordPlus | NA3SBS4 | - |
dc.subject.keywordPlus | NA11SN2PS12 | - |
dc.subject.keywordPlus | PERSPECTIVE | - |
dc.subject.keywordPlus | DYNAMICS | - |
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