There are no files associated with this item.
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 3395 | - |
dc.citation.number | 12 | - |
dc.citation.startPage | 3387 | - |
dc.citation.title | GREEN CHEMISTRY | - |
dc.citation.volume | 15 | - |
dc.contributor.author | Kim, Jae Yul | - |
dc.contributor.author | Jang, Ji-Wook | - |
dc.contributor.author | Youn, Duck Hyun | - |
dc.contributor.author | Kim, Eun Sun | - |
dc.contributor.author | Choi, Sun Hee | - |
dc.contributor.author | Shin, Tae Joo | - |
dc.contributor.author | Lee, Jae Sung | - |
dc.date.accessioned | 2023-12-22T03:11:35Z | - |
dc.date.available | 2023-12-22T03:11:35Z | - |
dc.date.created | 2013-12-06 | - |
dc.date.issued | 2013-12 | - |
dc.description.abstract | Extraordinarily high selectivity (80-93%) for the oxyfunctionalization of the terminal methyl group was discovered in the photocatalytic selective oxidation of dodecane with molecular oxygen in a continuous flow system under mild gas phase reaction conditions over mesoporous TiO2-SiO 2 mixed oxide photocatalysts. The oxygenated hydrocarbon products were mainly aldehydes with carboxylic acids and ketones as minor products. By dispersing most of the Ti atomically in a tetrahedral coordination in a SiO 2 matrix, the oxygenated products were stabilized by diluting contiguous Ti sites present on the surface of TiO2 particles. The preferential oxidation of the terminal methyl group was ascribed to the extensive C-C bond breaking by photogenerated holes prior to oxyfunctionalization. | - |
dc.identifier.bibliographicCitation | GREEN CHEMISTRY, v.15, no.12, pp.3387 - 3395 | - |
dc.identifier.doi | 10.1039/c3gc41343h | - |
dc.identifier.issn | 1463-9262 | - |
dc.identifier.scopusid | 2-s2.0-84888216245 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/2508 | - |
dc.identifier.url | http://pubs.rsc.org/en/Content/ArticleLanding/2013/GC/c3gc41343h#!divAbstract | - |
dc.identifier.wosid | 000327459400013 | - |
dc.language | 영어 | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.title | Photocatalytic selective oxidation of the terminal methyl group of dodecane with molecular oxygen over atomically dispersed Ti in a mesoporous SiO2 matrix | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary; Green & Sustainable Science & Technology | - |
dc.relation.journalResearchArea | Chemistry; Science & Technology - Other Topics | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
Items in Repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Tel : 052-217-1404 / Email : scholarworks@unist.ac.kr
Copyright (c) 2023 by UNIST LIBRARY. All rights reserved.
ScholarWorks@UNIST was established as an OAK Project for the National Library of Korea.