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Seok, Sang Il
Laboratory for Energy Harvesting Materials and Systems (LEHMS)
Research Interests
  • Solar energy conversion, perovskite solar cells, inorganic-organic hybrid materials and processing, solution chemistry

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Key Factors Affecting the Performance of Sb2S3-sensitized Solar Cells During an Sb2S3 Deposition via SbCl3-thiourea Complex Solution-processing

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Title
Key Factors Affecting the Performance of Sb2S3-sensitized Solar Cells During an Sb2S3 Deposition via SbCl3-thiourea Complex Solution-processing
Author
Choi, Yong ChanSeok, Sangl IlHwang, EunjeongKim, Dae-Hwan
Issue Date
201807
Publisher
JOURNAL OF VISUALIZED EXPERIMENTS
Citation
JOVE-JOURNAL OF VISUALIZED EXPERIMENTS, v.137, no., pp.e58062 -
Abstract
Sb2S3 is considered as one of the emerging light absorbers that can be applied to next-generation solar cells because of its unique optical and electrical properties. Recently, we demonstrated its potential as next-generation solar cells by achieving a high photovoltaic efficiency of > 6% in Sb2S3-sensitized solar cells using a simple thiourea (TU)-based complex solution method. Here, we describe the key experimental procedures for the deposition of Sb2S3 on a mesoporous TiO2(mp-TiO2) layer using a SbCl3-TU complex solution in the fabrication of solar cells. First, the SbCl3-TU solution is synthesized by dissolving SbCl3 and TU in N,N-dimethylformamide at different molar ratios of SbCl3:TU. Then, the solution is deposited on as-prepared substrates consisting of mp-TiO2/TiO2-blocking layer/F-doped SnO2 glass by spin coating. Finally, to form crystalline Sb2S3, the samples are annealed in an N-2-filled glove box at 300 degrees C. The effects of the experimental parameters on the photovoltaic device performance are also discussed0
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DOI
http://dx.doi.org/10.3791/58062
ISSN
1940-087X
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