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Author

Lah, Myoung Soo
Nanoporous Materials Lab
Research Interests
  • Metal-Organic Frameworks (MOFs)

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A double-walled triangular metal-organic macrocycle based on a [Cu-2(COO)(4)] square paddle-wheel secondary building unit

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Title
A double-walled triangular metal-organic macrocycle based on a [Cu-2(COO)(4)] square paddle-wheel secondary building unit
Author
Song, XiaokaiLiu, XinfangOh, MinhakLah, Myoung Soo
Keywords
Dicarboxylic acid; Double-walled; Metal-organic; Rotational flexibility; Secondary building units; Triangular geometry
Issue Date
2010
Publisher
ROYAL SOC CHEMISTRY
Citation
DALTON TRANSACTIONS, v.39, no.27, pp.6178 - 6180
Abstract
A metal-organic macrocycle (MOM), [(Cu-2)(3)L-6(DMF)(2)(H2O)(4)], was prepared using a long and "pseudo-rigid" dicarboxylic acid, 1,4-bis(3-carboxylphenylethynyl) benzene (H2L), with some rotational flexibility, where the MOM has a double-walled triangular geometry with three Cu paddle-wheel secondary building units (SBUs) doubly connected by the ligands in a cis-conformation.
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DOI
http://dx.doi.org/10.1039/c0dt00185f
ISSN
1477-9226
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