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DC Field | Value | Language |
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dc.citation.endPage | 16623 | - |
dc.citation.number | 29 | - |
dc.citation.startPage | 16613 | - |
dc.citation.title | JOURNAL OF PHYSICAL CHEMISTRY C | - |
dc.citation.volume | 122 | - |
dc.contributor.author | Kim, Hee Su | - |
dc.contributor.author | Lee, Tack Ho | - |
dc.contributor.author | Yeop, Jiwoo | - |
dc.contributor.author | Cho, Hye Won | - |
dc.contributor.author | Kim, Jae Won | - |
dc.contributor.author | Park, Song Yi | - |
dc.contributor.author | Park, Jong Baek | - |
dc.contributor.author | Kim, Jin Young | - |
dc.contributor.author | Hwang, Do-Hoon | - |
dc.date.accessioned | 2023-12-21T20:37:15Z | - |
dc.date.available | 2023-12-21T20:37:15Z | - |
dc.date.created | 2018-08-30 | - |
dc.date.issued | 2018-07 | - |
dc.description.abstract | Semiconducting polymers consisting of (E)-1,2-di(thiophen-2-yl)ethene (TVT) derivatives and benzo[1,2-b:4,5-b']-dithiophene with conjugated thiophene side chains (BDTT) were designed and synthesized to investigate the effect of fluorine and cyano groups in the 3-position of the thiophene ring in TVT on the photovoltaic properties. The corresponding PBDTT-TVT, PBDTT-FTVT, and PBDTT-CNTVT copolymers containing TVT, difluoro TVT (FTVT), and dicyano TVT (CNTVT), respectively, demonstrated considerable variations in optical, electrochemical, morphological, and charge transporting properties. PBDTT-FTVT showed suitable frontier orbital energy levels, favorable face-on orientation, and a well-mixed and smooth morphology in the blends with 3,9-bis(2-methylene-(3-(1,1-dicyanomethylene)-indanone))-5,5,11,11-tetrakis(4-hexylphenyl)-dithieno[2,3-d:2',3'-d']-s-indaceno[1,2-b:5,6-b']dithiophene (ITIC) and [6,6]-phenyl-C-71-butyric acid methyl ester (PCBM). In contrast, PBDTT-CNTVT showed unfavorable frontier orbital energy levels and bimodal orientation in the thin-film state, which interrupted efficient charge transport in organic photovoltaic devices. The device fabricated using PBDTT-FTVT exhibited the highest power conversion efficiency (PCE) of up to 6.50% with ITIC and a slightly lower PCE of 6.35% with PCBM. | - |
dc.identifier.bibliographicCitation | JOURNAL OF PHYSICAL CHEMISTRY C, v.122, no.29, pp.16613 - 16623 | - |
dc.identifier.doi | 10.1021/acs.jpcc.8b05184 | - |
dc.identifier.issn | 1932-7447 | - |
dc.identifier.scopusid | 2-s2.0-85049908629 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/24746 | - |
dc.identifier.url | https://pubs.acs.org/doi/10.1021/acs.jpcc.8b05184 | - |
dc.identifier.wosid | 000440520500017 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Effect of Substituents of Thienylene-Vinylene-Thienylene-Based Conjugated Polymer Donors on the Performance of Fullerene and Nonfullerene Solar Cells | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary | - |
dc.relation.journalResearchArea | Chemistry; Science & Technology - Other Topics; Materials Science | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | FIELD-EFFECT TRANSISTORS | - |
dc.subject.keywordPlus | POWER CONVERSION EFFICIENCY | - |
dc.subject.keywordPlus | SEMICONDUCTING POLYMERS | - |
dc.subject.keywordPlus | CHARGE-CARRIER | - |
dc.subject.keywordPlus | BAND-GAP | - |
dc.subject.keywordPlus | ACCEPTOR | - |
dc.subject.keywordPlus | ELECTRON | - |
dc.subject.keywordPlus | RECOMBINATION | - |
dc.subject.keywordPlus | LIMITATIONS | - |
dc.subject.keywordPlus | COPOLYMERS | - |
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