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Author

Baek, Jong-Beom
Center for Dimension-Controllable Organic Frameworks
Research Interests
  • Covalent Organic Frameworks (COFs), Carbon Nanotubes(CNTs), graphene, Energy Conversion and Storage

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Edge-Selectively Functionalized Graphene Nanoplatelets

Cited 6 times inthomson ciCited 3 times inthomson ci
Title
Edge-Selectively Functionalized Graphene Nanoplatelets
Author
Chang, Dong WookChoi, Hyun-JungJeon, In-YupBaek, Jong-Beom
Keywords
acylation; chemical modification; energy conversion; graphene; nanostructures
Issue Date
201304
Publisher
WILEY-BLACKWELL
Citation
CHEMICAL RECORD, v.13, no.2, pp.224 - 238
Abstract
Graphene, as a single layer of graphite, is currently the focal point of research into condensed matter owing to its promising properties, such as exceptional mechanical strength, high thermal conductivity, large specific surface area, and ultrahigh electron-transport properties. Therefore, various physical and chemical synthetic procedures to prepare graphene and/or graphene nanoplatelets have been rapidly developed. Specifically, the synthesis of edge-selectively functionalized graphene (EFG) has been recently reported by using simple and scalable approaches, such as direct Friedel-Crafts acylation reactions in a mild acidic medium and a mechanochemical ball-milling process. In these approaches, chemical functionalization predominantly take place at the edges of the graphitic layers via the covalent attachment of targeted organic molecular wedges. In addition, the distortion of the crystalline structures in the basal plane, which is beneficial for preserving the unique properties of the graphitic framework, can be minimized. In addition, the efficient exfoliation of graphene can be achieved, owing to the strong repulsive forces from the covalently linked wedges and strong shear forces during the reaction. Furthermore, EFG shows promising potential in many useful applications, such as highly conductive large-area films, metal-free electrocatalysts for the oxygen-reduction reaction (ORR), and as additives in composite materials with enhanced properties. Herein, we summarize the recent progress and general aspects of EFG, including synthesis, reaction mechanism, properties, and applications.
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DOI
http://dx.doi.org/10.1002/tcr.201200032
ISSN
1527-8999
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