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DC Field | Value | Language |
---|---|---|
dc.citation.endPage | 44269 | - |
dc.citation.number | 51 | - |
dc.citation.startPage | 44264 | - |
dc.citation.title | ACS APPLIED MATERIALS & INTERFACES | - |
dc.citation.volume | 9 | - |
dc.contributor.author | Mazur, Tomasz | - |
dc.contributor.author | Lach, Slawomir | - |
dc.contributor.author | Grzybowski, Bartosz A. | - |
dc.date.accessioned | 2023-12-21T21:19:33Z | - |
dc.date.available | 2023-12-21T21:19:33Z | - |
dc.date.created | 2018-01-23 | - |
dc.date.issued | 2017-12 | - |
dc.description.abstract | A metal surface passivated with a tightly packed self assembled monolayer (SAM) can be made catalytically active upon the metal's mechanical deformation. This deformation renders the SAM sparser and exposes additional catalytic sites on the metal's surface. If the deformation is elastic, return of the metal to the original shape "heals" the SAM and nearly extinguishes the catalytic activity. Kelvin probe force microscopy and theoretical considerations both indicate that the catalytic domains "opening up" in the deformed SAM are of nanoscopic dimensions. | - |
dc.identifier.bibliographicCitation | ACS APPLIED MATERIALS & INTERFACES, v.9, no.51, pp.44264 - 44269 | - |
dc.identifier.doi | 10.1021/acsami.7b15253 | - |
dc.identifier.issn | 1944-8244 | - |
dc.identifier.scopusid | 2-s2.0-85037711195 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/23248 | - |
dc.identifier.url | http://pubs.acs.org/doi/10.1021/acsami.7b15253 | - |
dc.identifier.wosid | 000419082000002 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Heterogeneous Catalysis "On Demand": Mechanically Controlled Catalytic Activity of a Metal Surface | - |
dc.type | Article | - |
dc.description.isOpenAccess | FALSE | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology; Materials Science, Multidisciplinary | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics; Materials Science | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | heterogeneous catalysis "on demand" | - |
dc.subject.keywordAuthor | self-assembled monolayer | - |
dc.subject.keywordAuthor | mechanical deformation | - |
dc.subject.keywordAuthor | catalytic domains | - |
dc.subject.keywordPlus | SELF-ASSEMBLED MONOLAYERS | - |
dc.subject.keywordPlus | DIP-PEN NANOLITHOGRAPHY | - |
dc.subject.keywordPlus | LIGHT | - |
dc.subject.keywordPlus | POLYMERIZATION | - |
dc.subject.keywordPlus | NANOTECHNOLOGY | - |
dc.subject.keywordPlus | ORGANOCATALYST | - |
dc.subject.keywordPlus | NANOPARTICLES | - |
dc.subject.keywordPlus | CYCLODEXTRIN | - |
dc.subject.keywordPlus | PALLADIUM | - |
dc.subject.keywordPlus | SYSTEMS | - |
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