Full metadata record
DC Field | Value | Language |
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dc.citation.startPage | 1599 | - |
dc.citation.title | NATURE COMMUNICATIONS | - |
dc.citation.volume | 8 | - |
dc.contributor.author | Bae, Seo-Yoon | - |
dc.contributor.author | Kim, Dongwook | - |
dc.contributor.author | Shin, Dongbin | - |
dc.contributor.author | Mahmood, Javeed | - |
dc.contributor.author | Jeon, In-Yup | - |
dc.contributor.author | Jung, Sun-Min | - |
dc.contributor.author | Shin, Sun-Hee | - |
dc.contributor.author | Kim, Seok-Jin | - |
dc.contributor.author | Park, Noejung | - |
dc.contributor.author | Lah, Myoung Soo | - |
dc.contributor.author | Baek, Jong-Beom | - |
dc.date.accessioned | 2023-12-21T21:38:00Z | - |
dc.date.available | 2023-12-21T21:38:00Z | - |
dc.date.created | 2017-11-29 | - |
dc.date.issued | 2017-11 | - |
dc.description.abstract | Solid-state reaction of organic molecules holds a considerable advantage over liquid-phase processes in the manufacturing industry. However, the research progress in exploring this benefit is largely staggering, which leaves few liquid-phase systems to work with. Here, we show a synthetic protocol for the formation of a three-dimensional porous organic network via solid-state explosion of organic single crystals. The explosive reaction is realized by the Bergman reaction (cycloaromatization) of three enediyne groups on 2,3,6,7,14,15-hexaethynyl-9,10-dihydro-9,10-[1,2]benzenoanthracene. The origin of the explosion is systematically studied using single-crystal X-ray diffraction and differential scanning calorimetry, along with high-speed camera and density functional theory calculations. The results suggest that the solid-state explosion is triggered by an abrupt change in lattice energy induced by release of primer molecules in the 2,3,6,7,14,15-hexaethynyl-9,10-dihydro-9,10-[1,2]benzenoanthracene crystal lattice. | - |
dc.identifier.bibliographicCitation | NATURE COMMUNICATIONS, v.8, pp.1599 | - |
dc.identifier.doi | 10.1038/s41467-017-01568-3 | - |
dc.identifier.issn | 2041-1723 | - |
dc.identifier.scopusid | 2-s2.0-85034585495 | - |
dc.identifier.uri | https://scholarworks.unist.ac.kr/handle/201301/23000 | - |
dc.identifier.url | https://www.nature.com/articles/s41467-017-01568-3 | - |
dc.identifier.wosid | 000415649900001 | - |
dc.language | 영어 | - |
dc.publisher | NATURE PUBLISHING GROUP | - |
dc.title | Forming a three-dimensional porous organic network via solid-state explosion of organic single crystals | - |
dc.type | Article | - |
dc.description.isOpenAccess | TRUE | - |
dc.relation.journalWebOfScienceCategory | Multidisciplinary Sciences | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordPlus | 2-DIMENSIONAL POLYMER | - |
dc.subject.keywordPlus | SURFACE-AREA | - |
dc.subject.keywordPlus | INTRINSIC MICROPOROSITY | - |
dc.subject.keywordPlus | TRIPTYCENE | - |
dc.subject.keywordPlus | MEMBRANE | - |
dc.subject.keywordPlus | BENZYNE | - |
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